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• W2792671803 abstract "In this study, sulphur-modified reduced graphene oxide (S-rGO) was employed as substrate to investigate the growth mechanism of metal and metallic nanoparticles (NPs). It is observed that the monodispersed Au, SnO2, FeO(OH) and Co3S4 NPs in sub-nanometer (sub-nm) with narrow size distribution were successfully anchored on S-rGO, respectively. The results indicate that the S contained radicals, viz. the CS and CSC functional groups play an important role in determining the homogeneous distribution of NPs on S-rGO by providing active sites for the NPs anchoring and nucleation. In additional, as anode materials for lithium ion batteries (LIBs), the as-synthesized sub-nm sized Co3S4/S-rGO and SnO2/S-rGO composites show excellent Li storage performance. It could be stabilized at ca. 600 mAh/g after formation cycle with the coulombic efficiency of 98%. It is expected that the strategy of growing sub-nm sized metallic component onto graphene by applying sulphur functionalities could be utilized as a general method to prepare monodispersed graphene-based NPs with other metals, especially with transition metals in sub-nm sizes." @default.
• W2792671803 created "2018-03-29" @default.
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• W2792671803 date "2018-05-01" @default.
• W2792671803 modified "2023-10-06" @default.
• W2792671803 title "A general approach to homogeneous sub-nanometer metallic particle/graphene composites by S-coordinator" @default.
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• W2792671803 doi "https://doi.org/10.1016/j.ssc.2018.02.007" @default.
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