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- W2792691025 abstract "Abstract Formal synthesis of angiopterlactone B has been accomplished via. enantioselective reduction of ketone with Daucus carota , Sharpless dihydroxylation and Andos modified Horner‐Wadsworth‐Emmons (HWE) reagent to introduce Z ‐olefination. Here we evolved a new path for the synthesis of ( S,S )‐osmundalactone and 3–5 dihydroxy γ‐caprolactone. The initial synthetic route for both caprolactone and osmundalcactone build on biocatalytic process while in later case Sharpless dihydroxylation delivered required stereocentres. Z ‐selective olefination was utilized to furnish caprolactone which was further recycled in to 1‐(5‐oxotetrahydrofuran‐2yl) ethyl 2‐phenyl acetate. Both synthetic routes found to be applicable for many synthetic reactions." @default.
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- W2792691025 date "2018-02-05" @default.
- W2792691025 modified "2023-10-16" @default.
- W2792691025 title "Formal Synthesis of Angiopterlactone B via Enantioselective Reduction of Ketone with Daucus Carota Root" @default.
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- W2792691025 doi "https://doi.org/10.1002/slct.201703183" @default.
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