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- W2792836911 endingPage "1268" @default.
- W2792836911 startingPage "1256" @default.
- W2792836911 abstract "Cu(0) wire-catalyzed single electron transfer–living radical polymerization (SET-LRP) of (−)-menthyl acrylate, a biobased hydrophobic monomer, was investigated at 25 °C in ethanol, isopropanol, ethyl lactate, 2,2,2-trifluoroethanol (TFE), and 2,2,3,3-tetrafluoropropanol (TFP). All solvents are known to promote, in the presence of N ligands, the mechanistically required self-regulated disproportionation of Cu(I)Br into Cu(0) and Cu(II)Br2. Both fluorinated alcohols brought out their characteristics of universal SET-LRP solvents and showed the proper polarity balance to mediate an efficient polymerization of this bulky and hydrophobic monomer. Together with the secondary alkyl halide initiator, methyl 2-bromopropionate (MBP), and the tris(2-dimethylaminoethyl)amine (Me6-TREN) ligand, TFE and TPF mediated an efficient SET-LRP of MnA at room temperature that proceeds through a self-generated biphasic system. The results presented here demonstrate that Cu(0) wire-catalyzed SET-LRP can be used to target polyMnA with different block lengths and narrow molecular weight distribution at room temperature. Indeed, the use of a combination of techniques that include GPC, 1H NMR, MALDI-TOF MS performed before and after thioetherification of bromine terminus via “thio–bromo” click chemistry, and in situ reinitiation copolymerization experiments supports the near perfect chain end functionality of the synthesized biobased hydrophobic polymers. These results expand the possibilities of SET-LRP into the area of renewable resources where hydrophobic compounds are widespread." @default.
- W2792836911 created "2018-03-29" @default.
- W2792836911 creator A5017319587 @default.
- W2792836911 creator A5028683809 @default.
- W2792836911 creator A5067149287 @default.
- W2792836911 creator A5067785441 @default.
- W2792836911 creator A5083075585 @default.
- W2792836911 creator A5084942404 @default.
- W2792836911 date "2018-03-07" @default.
- W2792836911 modified "2023-10-15" @default.
- W2792836911 title "SET-LRP of the Hydrophobic Biobased Menthyl Acrylate" @default.
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