Matches in SemOpenAlex for { <https://semopenalex.org/work/W2792838370> ?p ?o ?g. }
- W2792838370 endingPage "978" @default.
- W2792838370 startingPage "971" @default.
- W2792838370 abstract "The reaction of the yttrium dialkyl precursor [N[Ph2PNC6H3(iPr)2]2Y(CH2SiMe3)2] (1) with more than 3 equiv of trimethylaluminum or triethylaluminum afforded the dinuclear heterometallic complexes N[Ph2PNC6H3(iPr)2]2Y{(μ-R)2AlR2}R (R = Me (2), Et (3)). When trimethylaluminum loading was reduced to 2 equiv, the same reaction gave the product N[Ph2PNC6H3(iPr)2]2Y{(μ-Me)2(μ-CH2SiMe3)AlMe}Me (4), with quite a different bonding mode. All of these complexes were characterized by NMR spectra, X-ray crystallography, and elemental analysis. We elucidated the step-reaction mechanism between the yttrium dialkyl complex based on bulky phosphazene ligand and trialkylaluminum, which might shed new light on the formation process of active species in organoaluminum-dependent Ziegler–Natta catalytic systems." @default.
- W2792838370 created "2018-03-29" @default.
- W2792838370 creator A5019498279 @default.
- W2792838370 creator A5022478306 @default.
- W2792838370 creator A5038777286 @default.
- W2792838370 creator A5047110002 @default.
- W2792838370 creator A5054519421 @default.
- W2792838370 creator A5062936568 @default.
- W2792838370 date "2018-03-12" @default.
- W2792838370 modified "2023-10-01" @default.
- W2792838370 title "Insights into the Formation Process of Yttrium–Aluminum Bimetallic Alkyl Complexes Supported by a Bulky Phosphazene Ligand" @default.
- W2792838370 cites W169320866 @default.
- W2792838370 cites W1822903239 @default.
- W2792838370 cites W1963772312 @default.
- W2792838370 cites W1966149855 @default.
- W2792838370 cites W1967839675 @default.
- W2792838370 cites W1968171191 @default.
- W2792838370 cites W1970403829 @default.
- W2792838370 cites W1982125147 @default.
- W2792838370 cites W1983582657 @default.
- W2792838370 cites W1983693673 @default.
- W2792838370 cites W1984158173 @default.
- W2792838370 cites W1985374457 @default.
- W2792838370 cites W1985840933 @default.
- W2792838370 cites W1987816775 @default.
- W2792838370 cites W1994567457 @default.
- W2792838370 cites W1994611757 @default.
- W2792838370 cites W1996894942 @default.
- W2792838370 cites W1997075852 @default.
- W2792838370 cites W2003460160 @default.
- W2792838370 cites W2003855844 @default.
- W2792838370 cites W2010697685 @default.
- W2792838370 cites W2011615556 @default.
- W2792838370 cites W2018404012 @default.
- W2792838370 cites W2023972889 @default.
- W2792838370 cites W2024728997 @default.
- W2792838370 cites W2025191996 @default.
- W2792838370 cites W2031435093 @default.
- W2792838370 cites W2031980562 @default.
- W2792838370 cites W2032117139 @default.
- W2792838370 cites W2035293669 @default.
- W2792838370 cites W2036107850 @default.
- W2792838370 cites W2036137418 @default.
- W2792838370 cites W2042802630 @default.
- W2792838370 cites W2042975218 @default.
- W2792838370 cites W2044435721 @default.
- W2792838370 cites W2045031649 @default.
- W2792838370 cites W2046950139 @default.
- W2792838370 cites W2049872290 @default.
- W2792838370 cites W2050941357 @default.
- W2792838370 cites W2055323319 @default.
- W2792838370 cites W2059953115 @default.
- W2792838370 cites W2066719670 @default.
- W2792838370 cites W2067451258 @default.
- W2792838370 cites W2070556015 @default.
- W2792838370 cites W2072313401 @default.
- W2792838370 cites W2080391404 @default.
- W2792838370 cites W2083054778 @default.
- W2792838370 cites W2085558178 @default.
- W2792838370 cites W2087544550 @default.
- W2792838370 cites W2088578658 @default.
- W2792838370 cites W2091207238 @default.
- W2792838370 cites W2093677718 @default.
- W2792838370 cites W2097821787 @default.
- W2792838370 cites W2103986047 @default.
- W2792838370 cites W2110083079 @default.
- W2792838370 cites W2112304442 @default.
- W2792838370 cites W2112364346 @default.
- W2792838370 cites W2112809354 @default.
- W2792838370 cites W2112868409 @default.
- W2792838370 cites W2118741880 @default.
- W2792838370 cites W2119048414 @default.
- W2792838370 cites W2122205610 @default.
- W2792838370 cites W2129179838 @default.
- W2792838370 cites W2137589499 @default.
- W2792838370 cites W2138666421 @default.
- W2792838370 cites W2141120292 @default.
- W2792838370 cites W2142859582 @default.
- W2792838370 cites W2143263499 @default.
- W2792838370 cites W2154455185 @default.
- W2792838370 cites W2159529237 @default.
- W2792838370 cites W2159633808 @default.
- W2792838370 cites W2164696043 @default.
- W2792838370 cites W2167394988 @default.
- W2792838370 cites W2237373475 @default.
- W2792838370 cites W2312267508 @default.
- W2792838370 cites W2314163261 @default.
- W2792838370 cites W2314587060 @default.
- W2792838370 cites W2316291546 @default.
- W2792838370 cites W2317932091 @default.
- W2792838370 cites W2318930721 @default.
- W2792838370 cites W2319573595 @default.
- W2792838370 cites W2321177716 @default.
- W2792838370 cites W2326661697 @default.
- W2792838370 cites W2332789863 @default.
- W2792838370 cites W2333448090 @default.
- W2792838370 cites W2418701396 @default.
- W2792838370 cites W2510334707 @default.