Matches in SemOpenAlex for { <https://semopenalex.org/work/W2792845953> ?p ?o ?g. }
- W2792845953 endingPage "2215" @default.
- W2792845953 startingPage "2211" @default.
- W2792845953 abstract "Abstract We recently developed a divergent strategy for the synthesis of all eight possible 2,3,6‐trideoxyhexopyranosides with three stereogenic centers. However, the diastereoselectivity for one of the three stereogenic centers was low and it was not controlled by catalysts. In this update, we described a systematic method for the first catalytic asymmetric synthesis of all eight possible 2,3,6‐trideoxyhexopyranosides and all eight possible 2,3,4,6‐tetradeoxy‐4‐aminohexopyranosides. The products derived from this strategy include the glycone of natural products grecocycline A, spinosyn A, and ossamycin. All three stereogenic centers in each product was controlled by a pair of chiral catalysts. The key to the success is the application of our recently developed dynamic kinetic stereodivergent acylation of Achmatowicz rearrangement products and chiral catalyst‐directed reduction. Simple dimethylation of the 2,3,4,6‐tetradeoxy‐4‐amino sugars afforded derivatives of naturally occurring β‐D‐forosaminide and β‐L‐ossaminide. magnified image" @default.
- W2792845953 created "2018-03-29" @default.
- W2792845953 creator A5003103740 @default.
- W2792845953 creator A5066589762 @default.
- W2792845953 creator A5068409217 @default.
- W2792845953 creator A5087354808 @default.
- W2792845953 date "2018-04-14" @default.
- W2792845953 modified "2023-09-27" @default.
- W2792845953 title "Catalytic Asymmetric Synthesis of All Possible Stereoisomers of 2,3,4,6-Tetradeoxy-4-Aminohexopyranosides" @default.
- W2792845953 cites W1538840751 @default.
- W2792845953 cites W1578519026 @default.
- W2792845953 cites W1966987331 @default.
- W2792845953 cites W1968407876 @default.
- W2792845953 cites W1972029311 @default.
- W2792845953 cites W1972503264 @default.
- W2792845953 cites W1973637689 @default.
- W2792845953 cites W1977290228 @default.
- W2792845953 cites W1978159158 @default.
- W2792845953 cites W1985622929 @default.
- W2792845953 cites W1987156352 @default.
- W2792845953 cites W1992563538 @default.
- W2792845953 cites W1995353363 @default.
- W2792845953 cites W2007443092 @default.
- W2792845953 cites W2007903486 @default.
- W2792845953 cites W2012404114 @default.
- W2792845953 cites W2015589700 @default.
- W2792845953 cites W2027472161 @default.
- W2792845953 cites W2029435281 @default.
- W2792845953 cites W2029803644 @default.
- W2792845953 cites W2048863027 @default.
- W2792845953 cites W2059377297 @default.
- W2792845953 cites W2069201015 @default.
- W2792845953 cites W2074751883 @default.
- W2792845953 cites W2076139748 @default.
- W2792845953 cites W2084700417 @default.
- W2792845953 cites W2086758337 @default.
- W2792845953 cites W2090822821 @default.
- W2792845953 cites W2097506364 @default.
- W2792845953 cites W2103549259 @default.
- W2792845953 cites W2132358637 @default.
- W2792845953 cites W2135099599 @default.
- W2792845953 cites W2137781239 @default.
- W2792845953 cites W2143530845 @default.
- W2792845953 cites W2151228214 @default.
- W2792845953 cites W2151415261 @default.
- W2792845953 cites W2153799075 @default.
- W2792845953 cites W2157829302 @default.
- W2792845953 cites W2177066434 @default.
- W2792845953 cites W2181217954 @default.
- W2792845953 cites W2319872330 @default.
- W2792845953 cites W2332618095 @default.
- W2792845953 cites W2347203314 @default.
- W2792845953 cites W2410438845 @default.
- W2792845953 cites W2484843303 @default.
- W2792845953 cites W2490207288 @default.
- W2792845953 cites W2561498589 @default.
- W2792845953 cites W2577002300 @default.
- W2792845953 cites W2601818854 @default.
- W2792845953 cites W2949605228 @default.
- W2792845953 cites W2950614217 @default.
- W2792845953 cites W2951663609 @default.
- W2792845953 cites W2952265811 @default.
- W2792845953 doi "https://doi.org/10.1002/adsc.201800029" @default.
- W2792845953 hasPublicationYear "2018" @default.
- W2792845953 type Work @default.
- W2792845953 sameAs 2792845953 @default.
- W2792845953 citedByCount "5" @default.
- W2792845953 countsByYear W27928459532021 @default.
- W2792845953 countsByYear W27928459532022 @default.
- W2792845953 crossrefType "journal-article" @default.
- W2792845953 hasAuthorship W2792845953A5003103740 @default.
- W2792845953 hasAuthorship W2792845953A5066589762 @default.
- W2792845953 hasAuthorship W2792845953A5068409217 @default.
- W2792845953 hasAuthorship W2792845953A5087354808 @default.
- W2792845953 hasConcept C134195300 @default.
- W2792845953 hasConcept C146686406 @default.
- W2792845953 hasConcept C161790260 @default.
- W2792845953 hasConcept C178790620 @default.
- W2792845953 hasConcept C185592680 @default.
- W2792845953 hasConcept C193557335 @default.
- W2792845953 hasConcept C21951064 @default.
- W2792845953 hasConcept C2779396153 @default.
- W2792845953 hasConcept C28173026 @default.
- W2792845953 hasConcept C71240020 @default.
- W2792845953 hasConceptScore W2792845953C134195300 @default.
- W2792845953 hasConceptScore W2792845953C146686406 @default.
- W2792845953 hasConceptScore W2792845953C161790260 @default.
- W2792845953 hasConceptScore W2792845953C178790620 @default.
- W2792845953 hasConceptScore W2792845953C185592680 @default.
- W2792845953 hasConceptScore W2792845953C193557335 @default.
- W2792845953 hasConceptScore W2792845953C21951064 @default.
- W2792845953 hasConceptScore W2792845953C2779396153 @default.
- W2792845953 hasConceptScore W2792845953C28173026 @default.
- W2792845953 hasConceptScore W2792845953C71240020 @default.
- W2792845953 hasFunder F4320309434 @default.
- W2792845953 hasIssue "11" @default.
- W2792845953 hasLocation W27928459531 @default.
- W2792845953 hasOpenAccess W2792845953 @default.