Matches in SemOpenAlex for { <https://semopenalex.org/work/W2792906185> ?p ?o ?g. }
- W2792906185 endingPage "4956" @default.
- W2792906185 startingPage "4952" @default.
- W2792906185 abstract "Abstract Aerobic catalytic oxidations are promising routes to replace environmentally harmful oxidants with O 2 in organic syntheses. Here, we report a molecular barium vanadium oxide, [Ba 4 (dmso) 14 V 14 O 38 (NO 3 )] (= {Ba 4 V 14 } ) as viable homogeneous catalyst for a series of oxidation reactions in N , N ‐dimethyl formamide solution under oxygen (8 bar). Starting from the model compound 9,10‐dihydroanthracene, we report initial dehydrogenation/ aromatization leading to anthracene formation; this intermediate is subsequently oxidized by stepwise oxygen transfer, first giving the mono‐oxygenated anthrone and then the di‐oxygenated target product, anthraquinone. Comparative reaction analyses using the Neumann catalyst [PV 2 Mo 10 O 40 ] 5− as reference show that oxygen diffusion into the reaction mixture is the rate‐limiting step, resulting in accumulation of the reduced catalyst species. This allows us to propose improved reactor designs to overcome this fundamental challenge for aerobic oxidation catalysis." @default.
- W2792906185 created "2018-03-29" @default.
- W2792906185 creator A5012757987 @default.
- W2792906185 creator A5016937736 @default.
- W2792906185 creator A5054925318 @default.
- W2792906185 creator A5077390306 @default.
- W2792906185 creator A5080329256 @default.
- W2792906185 date "2018-03-02" @default.
- W2792906185 modified "2023-09-30" @default.
- W2792906185 title "Aerobic Oxidation Catalysis by a Molecular Barium Vanadium Oxide" @default.
- W2792906185 cites W1830355703 @default.
- W2792906185 cites W1966968966 @default.
- W2792906185 cites W1972497838 @default.
- W2792906185 cites W1973587249 @default.
- W2792906185 cites W1982709053 @default.
- W2792906185 cites W1983442729 @default.
- W2792906185 cites W2004999950 @default.
- W2792906185 cites W2015288243 @default.
- W2792906185 cites W2015729676 @default.
- W2792906185 cites W2018566072 @default.
- W2792906185 cites W2019901122 @default.
- W2792906185 cites W2024808440 @default.
- W2792906185 cites W2029964531 @default.
- W2792906185 cites W2033220920 @default.
- W2792906185 cites W2034063945 @default.
- W2792906185 cites W2045842382 @default.
- W2792906185 cites W2047492063 @default.
- W2792906185 cites W2051306215 @default.
- W2792906185 cites W2063162795 @default.
- W2792906185 cites W2067155573 @default.
- W2792906185 cites W2080901812 @default.
- W2792906185 cites W2087498102 @default.
- W2792906185 cites W2102320007 @default.
- W2792906185 cites W2119735967 @default.
- W2792906185 cites W2128172145 @default.
- W2792906185 cites W2130993910 @default.
- W2792906185 cites W2144828032 @default.
- W2792906185 cites W2167221661 @default.
- W2792906185 cites W2300440225 @default.
- W2792906185 cites W2313576386 @default.
- W2792906185 cites W2318578521 @default.
- W2792906185 cites W2516696608 @default.
- W2792906185 cites W2734746909 @default.
- W2792906185 cites W2754953707 @default.
- W2792906185 cites W2761270525 @default.
- W2792906185 cites W2949995704 @default.
- W2792906185 cites W4251645953 @default.
- W2792906185 doi "https://doi.org/10.1002/chem.201706046" @default.
- W2792906185 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29438588" @default.
- W2792906185 hasPublicationYear "2018" @default.
- W2792906185 type Work @default.
- W2792906185 sameAs 2792906185 @default.
- W2792906185 citedByCount "17" @default.
- W2792906185 countsByYear W27929061852018 @default.
- W2792906185 countsByYear W27929061852019 @default.
- W2792906185 countsByYear W27929061852020 @default.
- W2792906185 countsByYear W27929061852021 @default.
- W2792906185 countsByYear W27929061852022 @default.
- W2792906185 countsByYear W27929061852023 @default.
- W2792906185 crossrefType "journal-article" @default.
- W2792906185 hasAuthorship W2792906185A5012757987 @default.
- W2792906185 hasAuthorship W2792906185A5016937736 @default.
- W2792906185 hasAuthorship W2792906185A5054925318 @default.
- W2792906185 hasAuthorship W2792906185A5077390306 @default.
- W2792906185 hasAuthorship W2792906185A5080329256 @default.
- W2792906185 hasConcept C118792377 @default.
- W2792906185 hasConcept C119889771 @default.
- W2792906185 hasConcept C161790260 @default.
- W2792906185 hasConcept C178790620 @default.
- W2792906185 hasConcept C179104552 @default.
- W2792906185 hasConcept C185592680 @default.
- W2792906185 hasConcept C2776820632 @default.
- W2792906185 hasConcept C2778496505 @default.
- W2792906185 hasConcept C2778913731 @default.
- W2792906185 hasConcept C2779563022 @default.
- W2792906185 hasConcept C504678139 @default.
- W2792906185 hasConcept C540031477 @default.
- W2792906185 hasConcept C55904794 @default.
- W2792906185 hasConcept C75473681 @default.
- W2792906185 hasConceptScore W2792906185C118792377 @default.
- W2792906185 hasConceptScore W2792906185C119889771 @default.
- W2792906185 hasConceptScore W2792906185C161790260 @default.
- W2792906185 hasConceptScore W2792906185C178790620 @default.
- W2792906185 hasConceptScore W2792906185C179104552 @default.
- W2792906185 hasConceptScore W2792906185C185592680 @default.
- W2792906185 hasConceptScore W2792906185C2776820632 @default.
- W2792906185 hasConceptScore W2792906185C2778496505 @default.
- W2792906185 hasConceptScore W2792906185C2778913731 @default.
- W2792906185 hasConceptScore W2792906185C2779563022 @default.
- W2792906185 hasConceptScore W2792906185C504678139 @default.
- W2792906185 hasConceptScore W2792906185C540031477 @default.
- W2792906185 hasConceptScore W2792906185C55904794 @default.
- W2792906185 hasConceptScore W2792906185C75473681 @default.
- W2792906185 hasFunder F4320328198 @default.
- W2792906185 hasIssue "19" @default.
- W2792906185 hasLocation W27929061851 @default.
- W2792906185 hasLocation W27929061852 @default.
- W2792906185 hasOpenAccess W2792906185 @default.