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- W2792989466 abstract "Abstract Alkylidene‐bridged scandium–copper/silver heterobimetallic complexes were synthesized and structurally characterized. The complexes contain different Sc−C and M−C (M=Cu I , Ag I ) bonds. The reactivity of the scandium–copper heterobimetallic complex was also studied, which reveals that the heterobimetallic complex is a reaction intermediate for the transmetalation of akylidene group from Sc III to Cu I . The scandium–copper heterobimetallic complex also undergoes an addition reaction with CO, resulting in the formation of a new C=C double bond. DFT calculations were used to study the bonding and the subsequent reactivity with CO of the scandium–copper heterobimetallic complex. It clearly demonstrates a cooperative effect between the two metal centers through the formation of a direct Sc⋅⋅⋅Cu interaction that drives the reactivity with CO." @default.
- W2792989466 created "2018-03-29" @default.
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- W2792989466 date "2018-03-09" @default.
- W2792989466 modified "2023-10-18" @default.
- W2792989466 title "Dianionic Carbon-Bridged Scandium-Copper/Silver Heterobimetallic Complexes: Synthesis, Bonding, and Reactivity" @default.
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- W2792989466 doi "https://doi.org/10.1002/chem.201706147" @default.
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