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- W2793004311 endingPage "4394" @default.
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- W2793004311 abstract "Separations of f-block elements are a critical aspect of nuclear waste processing. Redox-based separations offer promise, but challenges remain in stabilizing and differentiating actinides in high oxidation states. The investigation of new ligand types that provide thermodynamic stabilization to high-valent actinides is essential for expanding their fundamental chemistry and to elaborate new separation techniques and storage methods. We report herein the preparation and characterization of Th and U complexes of the pyridyl-hydroxylamine ligand, N-tert-butyl-N-(pyridin-2-yl)hydroxylamine (pyNO–). Electrochemical studies performed on the homoleptic complexes [M(pyNO)4] (M = Th, U) revealed significant stabilization of the U complex upon one-electron oxidation. The salt [U(pyNO)4]+ was isolated by chemical oxidation of [U(pyNO)4]; spectroscopic and computational data support assignment as a UV cation." @default.
- W2793004311 created "2018-03-29" @default.
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- W2793004311 creator A5086955828 @default.
- W2793004311 date "2018-03-23" @default.
- W2793004311 modified "2023-10-18" @default.
- W2793004311 title "Coordination Chemistry of a Strongly-Donating Hydroxylamine with Early Actinides: An Investigation of Redox Properties and Electronic Structure" @default.
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- W2793004311 doi "https://doi.org/10.1021/acs.inorgchem.7b03238" @default.
- W2793004311 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29569906" @default.
- W2793004311 hasPublicationYear "2018" @default.
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