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- W2793039965 abstract "The fungus Aspergillus japonicus MF275 produces himeic acid A (1), containing a 4-pyrone ring, along with its congeners, himeic acids B (2) and C (3). During culture, 1 was gradually converted to 3, the corresponding 4-pyridone derivative. A study of the relationship between the culture pH and the fungal metabolites showed that a decrease from pH 6.5 to pH 2 is essential for production of 1, while a subsequent increase to pH 5 is necessary for production of 3. In addition, we revealed that 1 was non-enzymatically converted to 3 by the incorporation of an ammonium nitrogen atom in a pH 5 buffer, and that 1 was converted to 2 at a conversion ratio of 50% during incubation in MeOH for five days." @default.
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- W2793039965 date "2018-05-01" @default.
- W2793039965 modified "2023-10-11" @default.
- W2793039965 title "pH-dependent production of himeic acid A and its non-enzymatic conversions to himeic acids B and C" @default.
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- W2793039965 doi "https://doi.org/10.1016/j.bmc.2018.02.034" @default.
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