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- W2793063485 abstract "Abstract The first palladium‐catalyzed decarboxylative coupling reactions of alkynyl carboxylic acids or α, β‐unsaturated carboxylic acids with 1‐Boc‐3‐iodoazetidine were described. The strategy could efficiently mediate β‐hydride elimination/migratory insertion sequence and selectively form 2‐alkynylazetidines (10 examples) and 3‐alkynylazetidines (15 examples) with high regioselectivity. The protocol provides convienient access to a variety of useful 3‐vinylazetidines in moderate yields (42%–72%) with good stereoselectivity. Notable advantages of this method include easy operation, mild reaction conditions, and wide substrate scope. magnified image" @default.
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- W2793063485 date "2018-05-02" @default.
- W2793063485 modified "2023-10-05" @default.
- W2793063485 title "Palladium-Catalyzed Decarboxylative Cross-Couplings of 1-Boc-3-iodoazetidine: Regioselective Access to 2-Alkynylazetidines, 3-Alkynylazetidines and 3-Vinylazetidines" @default.
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- W2793063485 doi "https://doi.org/10.1002/adsc.201800100" @default.
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