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- W2793177593 abstract "Abstract A new diphosphate Rb2CaP2O7 is synthesized by solid-states reaction. This compound crystallizes in the monoclinic space group of P21/n, with unit cell parameters of a=10.0238(9) A, b=5.7861(5) A, c=13.0654(11) A and β=104.726°. In this compound the [P2O7]4- dimers and [CaO6]10- units are interconnected by sharing the corner O atoms to form a 3D framework, with Rb+ cations filling in the interstices to balance the charge. The thermal property, IR and Raman spectra, UV–Vis–NIR diffuse reflectance spectrum and electronic band structure in Rb2CaP2O7 are determined, demonstrating its congruently melted characteristic and wide transparency down to the deep-ultraviolet region. Moreover, the replacement of Rb by K atoms in Rb2CaP2O7 can keep the compound structure unchanged, and the exemplified K1.85Rb0.15CaP2O7 exhibits almost the same fundamental physicochemical properties as Rb2CaP2O7." @default.
- W2793177593 created "2018-03-29" @default.
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- W2793177593 date "2018-05-01" @default.
- W2793177593 modified "2023-09-29" @default.
- W2793177593 title "Synthesis, crystal structure and characterizations of a new diphosphate Rb2CaP2O7" @default.
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- W2793177593 doi "https://doi.org/10.1016/j.jallcom.2018.02.113" @default.
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