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• W2793230124 abstract "Symmetric sodium-ion batteries (SIBs) are considered as promising candidates for large-scale energy storage owing to the simplified manufacture and wide abundance of sodium resources. However, most symmetric SIBs suffer from suppressed energy density. Here, a superior congeneric Na4V2(PO4)3 anode is synthesized via electrochemical preintercalation, and a high energy density symmetric SIB (Na3V2(PO4)3 as a cathode and Na4V2(PO4)3 as an anode) based on the deepened redox couple of V4+/V2+ is built for the first time. When measured in half cell, both electrodes show stabilized electrochemical performance (over 3000 cycles). The symmetric SIBs exhibit an output voltage of 3.0 V and a cell-level energy density of 138 W h kg–1. Furthermore, the sodium storage mechanism under the expanded measurement range of 0.01–3.9 V is disclosed through an in situ X-ray diffraction technique." @default.
• W2793230124 created "2018-03-29" @default.
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• W2793230124 date "2018-03-01" @default.
• W2793230124 modified "2023-10-15" @default.
• W2793230124 title "3.0 V High Energy Density Symmetric Sodium-Ion Battery: Na₄V₂(PO₄)₃∥Na₃V₂(PO₄)₃" @default.
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• W2793230124 doi "https://doi.org/10.1021/acsami.7b16901" @default.
• W2793230124 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29493210" @default.
• W2793230124 hasPublicationYear "2018" @default.
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