Matches in SemOpenAlex for { <https://semopenalex.org/work/W2793244039> ?p ?o ?g. }
- W2793244039 endingPage "124304" @default.
- W2793244039 startingPage "124304" @default.
- W2793244039 abstract "The microwave spectrum of m-methylanisole (also known as 3-methylanisole, or 3-methoxytoluene) was measured using a pulsed molecular jet Fourier transform microwave spectrometer operating in the frequency range of 2–26.5 GHz. Quantum chemical calculations predicted two conformers with the methoxy group in trans or cis position related to the ring methyl group, both of which were assigned in the experimental spectrum. Due to the internal rotation of the ring methyl group, all rotational transitions introduced large A-E splittings up to several GHz, which were analyzed with a newly developed program, called aixPAM, working in the principal axis system. There are significant differences in the V3 potential barriers of 55.7693(90) cm−1 and 36.6342(84) cm−1 determined by fitting 223 and 320 torsional components of the cis and the trans conformer, respectively. These values were compared with those found in other m-substituted toluenes as well as in o- and p-methylanisole. A comparison between the aixPAM and the XIAM code (using a combined axis system) was also performed." @default.
- W2793244039 created "2018-03-29" @default.
- W2793244039 creator A5027213695 @default.
- W2793244039 creator A5041149826 @default.
- W2793244039 creator A5077050056 @default.
- W2793244039 date "2018-03-28" @default.
- W2793244039 modified "2023-09-30" @default.
- W2793244039 title "Conformational effects on the torsional barriers in <i>m</i>-methylanisole studied by microwave spectroscopy" @default.
- W2793244039 cites W1544900601 @default.
- W2793244039 cites W1891877895 @default.
- W2793244039 cites W1964092882 @default.
- W2793244039 cites W1974849625 @default.
- W2793244039 cites W1977522693 @default.
- W2793244039 cites W1987875220 @default.
- W2793244039 cites W1993070678 @default.
- W2793244039 cites W1993093894 @default.
- W2793244039 cites W1998922574 @default.
- W2793244039 cites W2004536916 @default.
- W2793244039 cites W2009889817 @default.
- W2793244039 cites W2029525725 @default.
- W2793244039 cites W2030307268 @default.
- W2793244039 cites W2030657171 @default.
- W2793244039 cites W2046297824 @default.
- W2793244039 cites W2050606125 @default.
- W2793244039 cites W2060459679 @default.
- W2793244039 cites W2061487797 @default.
- W2793244039 cites W2068979845 @default.
- W2793244039 cites W2073345598 @default.
- W2793244039 cites W2078655208 @default.
- W2793244039 cites W2086314835 @default.
- W2793244039 cites W2087509828 @default.
- W2793244039 cites W2091457414 @default.
- W2793244039 cites W2129503809 @default.
- W2793244039 cites W2146989449 @default.
- W2793244039 cites W2170454808 @default.
- W2793244039 cites W223517619 @default.
- W2793244039 cites W2314046578 @default.
- W2793244039 cites W2319560866 @default.
- W2793244039 cites W2322617237 @default.
- W2793244039 cites W2343645666 @default.
- W2793244039 cites W2399977676 @default.
- W2793244039 cites W2402135901 @default.
- W2793244039 cites W2514530139 @default.
- W2793244039 cites W2522470560 @default.
- W2793244039 cites W2530261951 @default.
- W2793244039 cites W2597610226 @default.
- W2793244039 cites W2612507181 @default.
- W2793244039 cites W2759726350 @default.
- W2793244039 doi "https://doi.org/10.1063/1.5016273" @default.
- W2793244039 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29604888" @default.
- W2793244039 hasPublicationYear "2018" @default.
- W2793244039 type Work @default.
- W2793244039 sameAs 2793244039 @default.
- W2793244039 citedByCount "27" @default.
- W2793244039 countsByYear W27932440392018 @default.
- W2793244039 countsByYear W27932440392019 @default.
- W2793244039 countsByYear W27932440392020 @default.
- W2793244039 countsByYear W27932440392021 @default.
- W2793244039 countsByYear W27932440392022 @default.
- W2793244039 countsByYear W27932440392023 @default.
- W2793244039 crossrefType "journal-article" @default.
- W2793244039 hasAuthorship W2793244039A5027213695 @default.
- W2793244039 hasAuthorship W2793244039A5041149826 @default.
- W2793244039 hasAuthorship W2793244039A5077050056 @default.
- W2793244039 hasBestOaLocation W27932440392 @default.
- W2793244039 hasConcept C113196181 @default.
- W2793244039 hasConcept C121332964 @default.
- W2793244039 hasConcept C178790620 @default.
- W2793244039 hasConcept C185592680 @default.
- W2793244039 hasConcept C18705241 @default.
- W2793244039 hasConcept C2778565081 @default.
- W2793244039 hasConcept C2780378348 @default.
- W2793244039 hasConcept C2781311116 @default.
- W2793244039 hasConcept C31100168 @default.
- W2793244039 hasConcept C32891209 @default.
- W2793244039 hasConcept C32909587 @default.
- W2793244039 hasConcept C43617362 @default.
- W2793244039 hasConcept C44838205 @default.
- W2793244039 hasConcept C62520636 @default.
- W2793244039 hasConceptScore W2793244039C113196181 @default.
- W2793244039 hasConceptScore W2793244039C121332964 @default.
- W2793244039 hasConceptScore W2793244039C178790620 @default.
- W2793244039 hasConceptScore W2793244039C185592680 @default.
- W2793244039 hasConceptScore W2793244039C18705241 @default.
- W2793244039 hasConceptScore W2793244039C2778565081 @default.
- W2793244039 hasConceptScore W2793244039C2780378348 @default.
- W2793244039 hasConceptScore W2793244039C2781311116 @default.
- W2793244039 hasConceptScore W2793244039C31100168 @default.
- W2793244039 hasConceptScore W2793244039C32891209 @default.
- W2793244039 hasConceptScore W2793244039C32909587 @default.
- W2793244039 hasConceptScore W2793244039C43617362 @default.
- W2793244039 hasConceptScore W2793244039C44838205 @default.
- W2793244039 hasConceptScore W2793244039C62520636 @default.
- W2793244039 hasIssue "12" @default.
- W2793244039 hasLocation W27932440391 @default.
- W2793244039 hasLocation W27932440392 @default.
- W2793244039 hasLocation W27932440393 @default.
- W2793244039 hasLocation W27932440394 @default.