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• W2793316786 abstract "Abstract Formic acid and formate derivatives as hydrogen source on the hydrogenation of para‐chloronitrobenzene ( p‐ CNB) over supported gold catalysts were investigated. The hydrogenation activity in various formate derivatives followed the order: HCOOH < HCOONa < HCOOK < HCOONH 4 , which was in accordance with the decrement of electronegativity of cation species in formate derivatives. Moreover, in the case of HCOONH 4 as hydrogen source, the p‐ CNB conversion could enhance ten‐fold as the hydrogen source of H 2 at 60 o C. This promotion effect was also found in other supported Au catalysts. These results provide a general alternative hydrogen source to replace conventional H 2 as reducing agent for fine chemical processes." @default.
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• W2793316786 date "2018-03-13" @default.
• W2793316786 modified "2023-10-13" @default.
• W2793316786 title "Formic Acid or Formate Derivatives as the In Situ Hydrogen Source in Au-Catalyzed Reduction of <i>para</i> -Chloronitrobenzene" @default.
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• W2793316786 doi "https://doi.org/10.1002/slct.201702863" @default.
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