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- W2793445377 abstract "Abstract Cyclic carbonates were synthesized via the coupling reaction of CO 2 with epoxides at ambient pressure. The reaction of atmospheric pressure CO 2 with styrene oxide (SO) was selected as the model reaction. The coupling reaction was investigated by varying a simple catalytic system composed of Lewis acid and quaternary ammonium salt, molar ratio of catalyst to substrate, solvent, and temperature. The yield of styrene carbonate (SC) reached 91.5% in the presence of ZnBr 2 /Bu 4 NBr at p (CO 2 )° = 0.1 MPa and 100°C for 4 h. The coupling reactions between CO 2 and a series of substrates including aliphatic and aromatic epoxides were also performed efficiently. Yields of cyclic carbonates in the range of 76.4–93.2% were achieved. © 2018 Society of Chemical Industry and John Wiley & Sons, Ltd." @default.
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- W2793445377 date "2018-02-27" @default.
- W2793445377 modified "2023-10-01" @default.
- W2793445377 title "Synthesis of cyclic carbonate via the coupling reaction of carbon dioxide with epoxide at ambient pressure" @default.
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- W2793445377 doi "https://doi.org/10.1002/ghg.1766" @default.
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