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- W2793670781 abstract "Three efficient methods for five‐membered ring carbocycle synthesis have been developed from simple starting materials using samarium(II) reagents. A Reformatsky aldol reaction proceeded efficiently with samarium(II) iodide using lithium bromide as an additive. A new intramolecular alkylation of a samarium enolate was realized with a pendant sulfonate ester leaving group. Pinacol cyclization of a simple diketone was also demonstrated giving a diol product in high stereoselectivity. A promising lead result has been established demonstrating enantioselectivity in a chiral ligand controlled Reformatsky aldol reaction." @default.
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- W2793670781 date "2018-04-25" @default.
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- W2793670781 title "Cyclopentane Formation from Flexible Precursors Using Samarium(II) Reagents" @default.
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- W2793670781 doi "https://doi.org/10.1002/ejoc.201800102" @default.
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