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- W2793788049 abstract "Many applications of deep eutectic solvents (DES) rely on exploitation of their unique yet complex liquid structures. Due to the ionic nature of the DES components, their diffuse structures are perturbed in the presence of a charged surface. We hypothesize that it is possible to perturb the bulk DES structure far (>100 nm) from a curved, charged surface with mesoscopic dimensions.We performed in situ, synchrotron-based ultra-small angle X-ray scattering (USAXS) experiments to study the solvent distribution near the surface of charged mesoporous silica particles (MPS) (≈0.5 µm in diameter) suspended in both water and a common type of DES (1:2 choline Cl-:ethylene glycol).A careful USAXS analysis reveals that the perturbation of electron density distribution within the DES extends ≈1 μm beyond the particle surface, and that this perturbation can be manipulated by the addition of salt ions (AgCl). The concentration of the pore-filling fluid is greatly reduced in the DES. Notably, we extracted the real-space structures of these fluctuations from the USAXS data using a simulated annealing approach that does not require a priori knowledge about the scattering form factor, and can be generalized to a wide range of complex small-angle scattering problems." @default.
- W2793788049 created "2018-03-29" @default.
- W2793788049 creator A5032340088 @default.
- W2793788049 creator A5053447705 @default.
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- W2793788049 date "2018-06-01" @default.
- W2793788049 modified "2023-10-14" @default.
- W2793788049 title "Extended hierarchical solvent perturbations from curved surfaces of mesoporous silica particles in a deep eutectic solvent" @default.
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- W2793788049 doi "https://doi.org/10.1016/j.jcis.2018.02.078" @default.
- W2793788049 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5991083" @default.
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