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- W2793883822 abstract "Abstract A novel manganese(III)‐mediated oxidative cyclization of readily accessible 1,2,3‐trisubstituted indoles is described. This unprecedented method enabled the efficient construction of a complex polycyclic scaffold bearing a spiro‐indoline motif and a lactone moiety in one step. Its synthetic utility was demonstrated in the total synthesis of lapidilectine B (in 18 steps) by employing a strategic regioselective ring‐expansion and a silver‐promoted allenic amine cyclization as the additional key elements." @default.
- W2793883822 created "2018-03-29" @default.
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- W2793883822 date "2018-04-17" @default.
- W2793883822 modified "2023-10-17" @default.
- W2793883822 title "Total Synthesis of Lapidilectine B Enabled by Manganese(III)‐Mediated Oxidative Cyclization of Indoles" @default.
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- W2793883822 doi "https://doi.org/10.1002/chem.201801312" @default.
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