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- W2793893549 endingPage "11" @default.
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- W2793893549 abstract "The interaction of 5-methyl-2-phenyl-4-[(8-quinolylhydrazono)]pyrazol-3-one (2) and 5-methyl-2-phenyl-4-(8-quinolylhydrazono)pyrazole-3-thione (4) with copper(II) acetate monohydrate under reflux in ethanol results in the formation of copper(II) azo chelates incorporating CuN4O2 (5) and CuN3S2 (6) chromophores. All the compounds were characterized with FT-IR, EPR, X-ray absorption spectroscopy and magnetic measurements. The structures of complexes 5 and 6 were determined by X-ray single-crystal diffraction. Complex 5 adopts a pseudo-octahedral geometry with a cis disposition of the oxygen atoms around the copper(II) centre, whilst in 6 the copper(II) ion displays a square-pyramidal geometry with a {N3S2} ligand environment." @default.
- W2793893549 created "2018-03-29" @default.
- W2793893549 creator A5012756209 @default.
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- W2793893549 creator A5079473382 @default.
- W2793893549 creator A5085363937 @default.
- W2793893549 date "2018-05-01" @default.
- W2793893549 modified "2023-10-14" @default.
- W2793893549 title "Synthesis, properties and structure of copper(II) complexes of quinolyl azo derivatives of pyrazole-5-one(thione)" @default.
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- W2793893549 doi "https://doi.org/10.1016/j.poly.2018.02.018" @default.
- W2793893549 hasPublicationYear "2018" @default.