Matches in SemOpenAlex for { <https://semopenalex.org/work/W2794139210> ?p ?o ?g. }
- W2794139210 endingPage "1992" @default.
- W2794139210 startingPage "1988" @default.
- W2794139210 abstract "Abstract Metal nanostructures are often used in bioelectrocatalytic systems to increase the electrode surface area or to improve the conductivity of biofilms. We demonstrate, that decreasing the size of gold nanoparticles below 2 nm may result in a change of the mechanism of electron transfer (ET) between the enzyme active site and the electrode from direct to mediated ET. Clusters with diameters smaller than 2 nm exhibited molecule‐like behavior reflected in the appearance of oxidation and reduction peaks separated by a clearly developed HOMO—LUMO gap. The redox activity of the nanoparticles was found to contribute to the ET mechanism of fructose dehydrogenase switching it to gold cluster mediated electron transfer instead of direct ET. In the presence of gold clusters at the electrode, the overpotential of the catalyzed fructose oxidation reaction was 100 mV lower and the catalytic reaction rate constant was 2.5 times larger confirming the unique mediating role of the Au clusters." @default.
- W2794139210 created "2018-03-29" @default.
- W2794139210 creator A5001474334 @default.
- W2794139210 creator A5022201417 @default.
- W2794139210 creator A5023090583 @default.
- W2794139210 creator A5056989984 @default.
- W2794139210 date "2018-03-05" @default.
- W2794139210 modified "2023-10-16" @default.
- W2794139210 title "Size Does Matter-Mediation of Electron Transfer by Gold Clusters in Bioelectrocatalysis" @default.
- W2794139210 cites W1813249491 @default.
- W2794139210 cites W1993000440 @default.
- W2794139210 cites W1993779520 @default.
- W2794139210 cites W1996588896 @default.
- W2794139210 cites W2003914285 @default.
- W2794139210 cites W2014687455 @default.
- W2794139210 cites W2041767737 @default.
- W2794139210 cites W2051498567 @default.
- W2794139210 cites W2059559745 @default.
- W2794139210 cites W2065125416 @default.
- W2794139210 cites W2066175031 @default.
- W2794139210 cites W2066286007 @default.
- W2794139210 cites W2081401218 @default.
- W2794139210 cites W2115803851 @default.
- W2794139210 cites W2236129896 @default.
- W2794139210 cites W2322023848 @default.
- W2794139210 cites W2343501567 @default.
- W2794139210 cites W2515286324 @default.
- W2794139210 cites W2604674849 @default.
- W2794139210 cites W2625444697 @default.
- W2794139210 cites W2766672439 @default.
- W2794139210 doi "https://doi.org/10.1002/cctc.201800032" @default.
- W2794139210 hasPublicationYear "2018" @default.
- W2794139210 type Work @default.
- W2794139210 sameAs 2794139210 @default.
- W2794139210 citedByCount "20" @default.
- W2794139210 countsByYear W27941392102018 @default.
- W2794139210 countsByYear W27941392102019 @default.
- W2794139210 countsByYear W27941392102020 @default.
- W2794139210 countsByYear W27941392102021 @default.
- W2794139210 countsByYear W27941392102022 @default.
- W2794139210 countsByYear W27941392102023 @default.
- W2794139210 crossrefType "journal-article" @default.
- W2794139210 hasAuthorship W2794139210A5001474334 @default.
- W2794139210 hasAuthorship W2794139210A5022201417 @default.
- W2794139210 hasAuthorship W2794139210A5023090583 @default.
- W2794139210 hasAuthorship W2794139210A5056989984 @default.
- W2794139210 hasConcept C104819515 @default.
- W2794139210 hasConcept C123669783 @default.
- W2794139210 hasConcept C147597530 @default.
- W2794139210 hasConcept C147789679 @default.
- W2794139210 hasConcept C152365726 @default.
- W2794139210 hasConcept C155672457 @default.
- W2794139210 hasConcept C161790260 @default.
- W2794139210 hasConcept C164866538 @default.
- W2794139210 hasConcept C171250308 @default.
- W2794139210 hasConcept C17525397 @default.
- W2794139210 hasConcept C178790620 @default.
- W2794139210 hasConcept C179104552 @default.
- W2794139210 hasConcept C185592680 @default.
- W2794139210 hasConcept C186460083 @default.
- W2794139210 hasConcept C192562407 @default.
- W2794139210 hasConcept C199360897 @default.
- W2794139210 hasConcept C24840226 @default.
- W2794139210 hasConcept C2779175510 @default.
- W2794139210 hasConcept C41008148 @default.
- W2794139210 hasConcept C52859227 @default.
- W2794139210 hasConcept C55493867 @default.
- W2794139210 hasConcept C55904794 @default.
- W2794139210 hasConcept C75473681 @default.
- W2794139210 hasConceptScore W2794139210C104819515 @default.
- W2794139210 hasConceptScore W2794139210C123669783 @default.
- W2794139210 hasConceptScore W2794139210C147597530 @default.
- W2794139210 hasConceptScore W2794139210C147789679 @default.
- W2794139210 hasConceptScore W2794139210C152365726 @default.
- W2794139210 hasConceptScore W2794139210C155672457 @default.
- W2794139210 hasConceptScore W2794139210C161790260 @default.
- W2794139210 hasConceptScore W2794139210C164866538 @default.
- W2794139210 hasConceptScore W2794139210C171250308 @default.
- W2794139210 hasConceptScore W2794139210C17525397 @default.
- W2794139210 hasConceptScore W2794139210C178790620 @default.
- W2794139210 hasConceptScore W2794139210C179104552 @default.
- W2794139210 hasConceptScore W2794139210C185592680 @default.
- W2794139210 hasConceptScore W2794139210C186460083 @default.
- W2794139210 hasConceptScore W2794139210C192562407 @default.
- W2794139210 hasConceptScore W2794139210C199360897 @default.
- W2794139210 hasConceptScore W2794139210C24840226 @default.
- W2794139210 hasConceptScore W2794139210C2779175510 @default.
- W2794139210 hasConceptScore W2794139210C41008148 @default.
- W2794139210 hasConceptScore W2794139210C52859227 @default.
- W2794139210 hasConceptScore W2794139210C55493867 @default.
- W2794139210 hasConceptScore W2794139210C55904794 @default.
- W2794139210 hasConceptScore W2794139210C75473681 @default.
- W2794139210 hasFunder F4320322511 @default.
- W2794139210 hasIssue "9" @default.
- W2794139210 hasLocation W27941392101 @default.
- W2794139210 hasOpenAccess W2794139210 @default.
- W2794139210 hasPrimaryLocation W27941392101 @default.
- W2794139210 hasRelatedWork W2000591187 @default.