FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2794257683> ?p ?o ?g. }

• W2794257683 endingPage "2048" @default.
• W2794257683 startingPage "2036" @default.
• W2794257683 abstract "Black phosphorus (bP) has been recently investigated for next generation nanoelectronic multifunctional devices. However, the intrinsic instability of exfoliated bP (the bP nanoflakes) towards both moisture and air has so far overshadowed its practical implementation. In order to contribute to fill this gap, we report here the preparation of new hybrid polymer-based materials where bP nanoflakes exhibit a significantly improved stability. The new materials have been prepared by different synthetic paths including: i) the mixing of conventionally liquid-phase exfoliated bP (in DMSO) with PMMA solution; ii) the direct exfoliation of bP in a polymeric solution; iii) the in situ radical polymerization after exfoliating bP in the liquid monomer (methyl methacrylate, MMA). This last methodology concerns the preparation of stable suspensions of bPn-MMA by sonication-assisted liquid phase exfoliation (LPE) of bP in the presence of MMA followed by radical polymerization. The hybrids characteristics have been compared in order to evaluate the bP dispersion and the effectiveness of the bPn interfacial interactions with polymer chains aimed at their long-term environmental stabilization. The passivation of bPn results particularly effective when the hybrid material is prepared by in situ polymerization. By using this synthetic methodology, the nanoflakes, even if with a gradient of dispersion (size of aggregates), preserve their chemical structure from oxidation (as proved by both Raman and 31P-Solid State NMR studies) and are particularly stable to air and UV light exposure." @default.
• W2794257683 created "2018-03-29" @default.
• W2794257683 creator A5004632551 @default.
• W2794257683 creator A5012857418 @default.
• W2794257683 creator A5017214018 @default.
• W2794257683 creator A5027305217 @default.
• W2794257683 creator A5027968887 @default.
• W2794257683 creator A5037667260 @default.
• W2794257683 creator A5042012512 @default.
• W2794257683 creator A5044645928 @default.
• W2794257683 creator A5045226267 @default.
• W2794257683 creator A5046137515 @default.
• W2794257683 creator A5068086173 @default.
• W2794257683 creator A5068308446 @default.
• W2794257683 creator A5075287034 @default.
• W2794257683 date "2018-02-28" @default.
• W2794257683 modified "2023-10-15" @default.
• W2794257683 title "Polymer-Based Black Phosphorus (bP) Hybrid Materials by in Situ Radical Polymerization: An Effective Tool To Exfoliate bP and Stabilize bP Nanoflakes" @default.
• W2794257683 cites W1506419662 @default.
• W2794257683 cites W1507594864 @default.
• W2794257683 cites W1779039046 @default.
• W2794257683 cites W1979326373 @default.
• W2794257683 cites W1987460858 @default.
• W2794257683 cites W2003133084 @default.
• W2794257683 cites W2015368818 @default.
• W2794257683 cites W2042425989 @default.
• W2794257683 cites W2047034128 @default.
• W2794257683 cites W2047205370 @default.
• W2794257683 cites W2078860984 @default.
• W2794257683 cites W2091337215 @default.
• W2794257683 cites W2094637607 @default.
• W2794257683 cites W2111156194 @default.
• W2794257683 cites W2120576892 @default.
• W2794257683 cites W2139027493 @default.
• W2794257683 cites W2150315430 @default.
• W2794257683 cites W2151516307 @default.
• W2794257683 cites W2184609107 @default.
• W2794257683 cites W2201724973 @default.
• W2794257683 cites W222089771 @default.
• W2794257683 cites W2257953547 @default.
• W2794257683 cites W2259650972 @default.
• W2794257683 cites W2271766149 @default.
• W2794257683 cites W2292848292 @default.
• W2794257683 cites W2339995837 @default.
• W2794257683 cites W2341807766 @default.
• W2794257683 cites W2345528437 @default.
• W2794257683 cites W2399945589 @default.
• W2794257683 cites W2405039867 @default.
• W2794257683 cites W2413336263 @default.
• W2794257683 cites W2475394561 @default.
• W2794257683 cites W2475607305 @default.
• W2794257683 cites W2498044963 @default.
• W2794257683 cites W2508680038 @default.
• W2794257683 cites W2513787064 @default.
• W2794257683 cites W2519508610 @default.
• W2794257683 cites W2546126965 @default.
• W2794257683 cites W2552271669 @default.
• W2794257683 cites W2558703563 @default.
• W2794257683 cites W2590602300 @default.
• W2794257683 cites W2590700441 @default.
• W2794257683 cites W2611970084 @default.
• W2794257683 cites W2615537985 @default.
• W2794257683 cites W2658258666 @default.
• W2794257683 cites W2725616153 @default.
• W2794257683 cites W2751796860 @default.
• W2794257683 cites W2782363240 @default.
• W2794257683 cites W2949501803 @default.
• W2794257683 cites W3101747384 @default.
• W2794257683 cites W3102211088 @default.
• W2794257683 cites W3106183465 @default.
• W2794257683 cites W3106384302 @default.
• W2794257683 cites W3106525853 @default.
• W2794257683 cites W4253843266 @default.
• W2794257683 doi "https://doi.org/10.1021/acs.chemmater.7b05298" @default.
• W2794257683 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5989699" @default.
• W2794257683 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29887671" @default.
• W2794257683 hasPublicationYear "2018" @default.
• W2794257683 type Work @default.
• W2794257683 sameAs 2794257683 @default.
• W2794257683 citedByCount "54" @default.
• W2794257683 countsByYear W27942576832018 @default.
• W2794257683 countsByYear W27942576832019 @default.
• W2794257683 countsByYear W27942576832020 @default.
• W2794257683 countsByYear W27942576832021 @default.
• W2794257683 countsByYear W27942576832022 @default.
• W2794257683 countsByYear W27942576832023 @default.
• W2794257683 crossrefType "journal-article" @default.
• W2794257683 hasAuthorship W2794257683A5004632551 @default.
• W2794257683 hasAuthorship W2794257683A5012857418 @default.
• W2794257683 hasAuthorship W2794257683A5017214018 @default.
• W2794257683 hasAuthorship W2794257683A5027305217 @default.
• W2794257683 hasAuthorship W2794257683A5027968887 @default.
• W2794257683 hasAuthorship W2794257683A5037667260 @default.
• W2794257683 hasAuthorship W2794257683A5042012512 @default.
• W2794257683 hasAuthorship W2794257683A5044645928 @default.
• W2794257683 hasAuthorship W2794257683A5045226267 @default.
• W2794257683 hasAuthorship W2794257683A5046137515 @default.
• W2794257683 hasAuthorship W2794257683A5068086173 @default.

• next