FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2794287724> ?p ?o ?g. }

• W2794287724 endingPage "2416" @default.
• W2794287724 startingPage "2409" @default.
• W2794287724 abstract "Photocatalytic oxidation of carboplatin, a platinum antineoplastic drug, has been investigated in aqueous heterogeneous solutions containing TiO2 photocatalysts. The current study, besides the photocatalytic degradation of the drug, examines the utilization of the photo-reduction process occurring on the surface of the catalyst, leading simultaneously to the photo-deposition and recovery of platinum. TiO2 photocatalytic process was evaluated for its ability to degrade the molecule of carboplatin and concurrently result in the synthesis of efficient platinum modified TiO2 catalysts. The degradation kinetic was studied under different operational conditions, such as type of photocatalyst, catalyst loading, initial pH and addition of electron acceptors. Three systems were evaluated namely, TiO2 P25 under UV-A and TiO2 Kronos vlp 7000 under UV-A or visible illumination, with respect to their activity for substrate degradation and mineralization and their ability to bind platinum on their surface during photocatalytic oxidation of the drug. The initial degradation rate (r0) decreased in the order TiO2 P25/UV-A > TiO2 Kronos vlp 7000/UV-A > TiO2 Kronos vlp 7000/visible light. For TiO2 P25/UV-A, the addition of 100 mg L−1 H2O2 increases slightly the initial mineralization rate, while degradation rates gradually decrease as photocatalysis takes place in neutral and alkaline pH. Phytotoxicity measurements, showed that heterogeneous photocatalytic oxidation in the presence of TiO2 P25 is capable of reducing the phytotoxicity of carboplatin. For TiO2 P25 and TiO2 Kronos vlp 7000 under UV-A illumination, photo-reduction and deposition of platinum is fully accomplished within 60 min of oxidation, while for TiO2 Kronos vlp 7000 in the presence of visible light, the percentage of platinum deposited on the surface of the catalyst reaches 40%. Platinum photo-deposition is feasible, employing TiO2 P25, even after the catalyst is reused. The synthesized platinum modified TiO2 P25, demonstrated higher photocatalytic efficiency in comparison to the bare one, leading to 100% degradation of the model pollutant malachite green and 40% DOC reduction, after 30 min of photo-oxidation." @default.
• W2794287724 created "2018-03-29" @default.
• W2794287724 creator A5005605159 @default.
• W2794287724 creator A5008053359 @default.
• W2794287724 creator A5015904948 @default.
• W2794287724 creator A5044028753 @default.
• W2794287724 creator A5064943796 @default.
• W2794287724 date "2018-04-01" @default.
• W2794287724 modified "2023-10-06" @default.
• W2794287724 title "Mineralization of the antineoplastic drug carboplatin by heterogeneous photocatalysis with simultaneous synthesis of platinum-modified TiO2 catalysts" @default.
• W2794287724 cites W152205938 @default.
• W2794287724 cites W1964427311 @default.
• W2794287724 cites W1964612744 @default.
• W2794287724 cites W1969571373 @default.
• W2794287724 cites W1987152934 @default.
• W2794287724 cites W1993926520 @default.
• W2794287724 cites W1998925155 @default.
• W2794287724 cites W2005783724 @default.
• W2794287724 cites W2009274552 @default.
• W2794287724 cites W2012279779 @default.
• W2794287724 cites W2021887638 @default.
• W2794287724 cites W2022559518 @default.
• W2794287724 cites W2022573674 @default.
• W2794287724 cites W2030946379 @default.
• W2794287724 cites W2035720380 @default.
• W2794287724 cites W2035749709 @default.
• W2794287724 cites W2042559672 @default.
• W2794287724 cites W2045065321 @default.
• W2794287724 cites W2050569993 @default.
• W2794287724 cites W2062053783 @default.
• W2794287724 cites W2062896064 @default.
• W2794287724 cites W2063085095 @default.
• W2794287724 cites W2069493359 @default.
• W2794287724 cites W2073002685 @default.
• W2794287724 cites W2077372196 @default.
• W2794287724 cites W2078615488 @default.
• W2794287724 cites W2089760213 @default.
• W2794287724 cites W2092443967 @default.
• W2794287724 cites W2093137280 @default.
• W2794287724 cites W2112736429 @default.
• W2794287724 cites W2114869154 @default.
• W2794287724 cites W2171226267 @default.
• W2794287724 cites W2172286489 @default.
• W2794287724 cites W2193448636 @default.
• W2794287724 cites W2199089377 @default.
• W2794287724 cites W2211132286 @default.
• W2794287724 cites W2416888298 @default.
• W2794287724 cites W2466500178 @default.
• W2794287724 cites W2577569319 @default.
• W2794287724 doi "https://doi.org/10.1016/j.jece.2018.03.036" @default.
• W2794287724 hasPublicationYear "2018" @default.
• W2794287724 type Work @default.
• W2794287724 sameAs 2794287724 @default.
• W2794287724 citedByCount "21" @default.
• W2794287724 countsByYear W27942877242019 @default.
• W2794287724 countsByYear W27942877242020 @default.
• W2794287724 countsByYear W27942877242021 @default.
• W2794287724 countsByYear W27942877242022 @default.
• W2794287724 countsByYear W27942877242023 @default.
• W2794287724 crossrefType "journal-article" @default.
• W2794287724 hasAuthorship W2794287724A5005605159 @default.
• W2794287724 hasAuthorship W2794287724A5008053359 @default.
• W2794287724 hasAuthorship W2794287724A5015904948 @default.
• W2794287724 hasAuthorship W2794287724A5044028753 @default.
• W2794287724 hasAuthorship W2794287724A5064943796 @default.
• W2794287724 hasConcept C104663316 @default.
• W2794287724 hasConcept C111696902 @default.
• W2794287724 hasConcept C141071460 @default.
• W2794287724 hasConcept C161790260 @default.
• W2794287724 hasConcept C178790620 @default.
• W2794287724 hasConcept C179104552 @default.
• W2794287724 hasConcept C185592680 @default.
• W2794287724 hasConcept C192562407 @default.
• W2794287724 hasConcept C2776694085 @default.
• W2794287724 hasConcept C2778239845 @default.
• W2794287724 hasConcept C2781451048 @default.
• W2794287724 hasConcept C49040817 @default.
• W2794287724 hasConcept C518104683 @default.
• W2794287724 hasConcept C537208039 @default.
• W2794287724 hasConcept C65165184 @default.
• W2794287724 hasConcept C71924100 @default.
• W2794287724 hasConcept C75473681 @default.
• W2794287724 hasConceptScore W2794287724C104663316 @default.
• W2794287724 hasConceptScore W2794287724C111696902 @default.
• W2794287724 hasConceptScore W2794287724C141071460 @default.
• W2794287724 hasConceptScore W2794287724C161790260 @default.
• W2794287724 hasConceptScore W2794287724C178790620 @default.
• W2794287724 hasConceptScore W2794287724C179104552 @default.
• W2794287724 hasConceptScore W2794287724C185592680 @default.
• W2794287724 hasConceptScore W2794287724C192562407 @default.
• W2794287724 hasConceptScore W2794287724C2776694085 @default.
• W2794287724 hasConceptScore W2794287724C2778239845 @default.
• W2794287724 hasConceptScore W2794287724C2781451048 @default.
• W2794287724 hasConceptScore W2794287724C49040817 @default.
• W2794287724 hasConceptScore W2794287724C518104683 @default.
• W2794287724 hasConceptScore W2794287724C537208039 @default.
• W2794287724 hasConceptScore W2794287724C65165184 @default.
• W2794287724 hasConceptScore W2794287724C71924100 @default.

• next