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• W2794683466 abstract "Numerous studies have reported that pollutant reduction rates by ferrous iron (Fe2+) are substantially enhanced in the presence of an iron (oxyhydr)oxide mineral. Developing a thermodynamic framework to explain this phenomenon has been historically difficult due to challenges in quantifying reduction potential (EH) values for oxide-bound Fe2+ species. Recently, our group demonstrated that EH values for hematite- and goethite-bound Fe2+ can be accurately calculated using Gibbs free energy of formation values. Here, we tested if calculated EH values for oxide-bound Fe2+ could be used to develop a free energy relationship capable of describing variations in reduction rate constants of substituted nitrobenzenes, a class of model pollutants that contain reducible aromatic nitro groups, using data collected here and compiled from the literature. All the data could be described by a single linear relationship between the logarithms of the surface-area-normalized rate constant (kSA) values and EH and pH values [log(kSA) = −EH/0.059 V – pH + 3.42]. This framework provides mechanistic insights into how the thermodynamic favorability of electron transfer from oxide-bound Fe2+ relates to redox reaction kinetics." @default.
• W2794683466 created "2018-04-06" @default.
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• W2794683466 date "2018-03-29" @default.
• W2794683466 modified "2023-10-18" @default.
• W2794683466 title "Linking Thermodynamics to Pollutant Reduction Kinetics by Fe²⁺ Bound to Iron Oxides" @default.
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• W2794683466 doi "https://doi.org/10.1021/acs.est.8b00481" @default.
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• W2794683466 hasPublicationYear "2018" @default.
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