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• W2795006085 endingPage "111" @default.
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• W2795006085 abstract "Abstract Metal-based catalysis has notably contributed to the chemical community mainly in environmental science. Various cobalt and iron based catalysts have shown great potential for powerful reactive species. However, the application of cobalt and iron based perovskite for aqueous phase oxidation still remains limited. In this study, Sr2FeCoO6 double perovskite oxide was synthesized and used for the first time as an effective heterogeneous magnetic catalyst for peroxymonosulfate activation to produce free reactive radicals. Bisphenol F (BPF), a new emergent compound, was used as a target contaminant to evaluate the performance of this combination. Sr2FeCoO6 exhibited superior catalytic performance to the single SrFeO3 and SrCoO3 nanocrystals. A synergetic catalytic effect was found between Co and Fe, probably due to the accelerated reduction of Fe. BPF removal depends on catalyst loading, temperature, BPF and PMS concentration. It was observed that Sr2FeCoO6 activates peroxymonosulfate heterogeneously, with its heterogeneity being more pronounced at neutral pH. Kinetics studies reveal that BPF degradation obeys pseudo First order kinetic with an activation energy of 14.085 KJ/mol and an apparent rate constant of 0.026 min−1. Under conditions of 0.45 g L−1 and 10−4 M PMS, the complete BPF degradation occurred within 90 min at neutral conditions. In addition, the degraded BPF had undergone more than 65% mineralization within 6 h. The combination of UV irradiation (254 nm) with the Sr2FeCoO6-PMS system induces a potential acceleration in the mineralization rate. The effects of humic acid, carbonate, bicarbonate and chloride were also evaluated. A total of 8 products were detected, and the associated degradation pathway was proposed. To identify the dominating reactive species generated in the Sr2CoFeO6/PMS system, radical quenching tests and in situ electron paramagnetic resonance analysis were performed. To our knowledge, this is the first study that documents the heterogeneous activation of peroxymonosulfate with cobalt-iron based double perovskite for the treatment of the new emergent compound Bisphenol F." @default.
• W2795006085 created "2018-04-06" @default.
• W2795006085 creator A5004352784 @default.
• W2795006085 creator A5045678483 @default.
• W2795006085 creator A5051692503 @default.
• W2795006085 creator A5052332620 @default.
• W2795006085 creator A5053369080 @default.
• W2795006085 creator A5068175005 @default.
• W2795006085 date "2018-10-01" @default.
• W2795006085 modified "2023-10-16" @default.
• W2795006085 title "Sulfate radical-mediated degradation and mineralization of bisphenol F in neutral medium by the novel magnetic Sr2CoFeO6 double perovskite oxide catalyzed peroxymonosulfate: Influence of co-existing chemicals and UV irradiation" @default.
• W2795006085 cites W1138025054 @default.
• W2795006085 cites W1860002421 @default.
• W2795006085 cites W1882289074 @default.
• W2795006085 cites W1926950498 @default.
• W2795006085 cites W1942733594 @default.
• W2795006085 cites W1964675752 @default.
• W2795006085 cites W1968610435 @default.
• W2795006085 cites W1972119071 @default.
• W2795006085 cites W1974066606 @default.
• W2795006085 cites W1974435265 @default.
• W2795006085 cites W1978843455 @default.
• W2795006085 cites W1982676349 @default.
• W2795006085 cites W1984951638 @default.
• W2795006085 cites W1988139604 @default.
• W2795006085 cites W1990053219 @default.
• W2795006085 cites W1994402399 @default.
• W2795006085 cites W2006104250 @default.
• W2795006085 cites W2008308368 @default.
• W2795006085 cites W2009765015 @default.
• W2795006085 cites W2010479638 @default.
• W2795006085 cites W2012858423 @default.
• W2795006085 cites W2017313611 @default.
• W2795006085 cites W2019635083 @default.
• W2795006085 cites W2019783449 @default.
• W2795006085 cites W2027206979 @default.
• W2795006085 cites W2030001290 @default.
• W2795006085 cites W2032533160 @default.
• W2795006085 cites W2032540896 @default.
• W2795006085 cites W2035429631 @default.
• W2795006085 cites W2036699846 @default.
• W2795006085 cites W2038173949 @default.
• W2795006085 cites W2041609470 @default.
• W2795006085 cites W2042049555 @default.
• W2795006085 cites W2045059986 @default.
• W2795006085 cites W2050755687 @default.
• W2795006085 cites W2052692121 @default.
• W2795006085 cites W2054759372 @default.
• W2795006085 cites W2058117092 @default.
• W2795006085 cites W2058454311 @default.
• W2795006085 cites W2062618008 @default.
• W2795006085 cites W2064265117 @default.
• W2795006085 cites W2064421483 @default.
• W2795006085 cites W2069916097 @default.
• W2795006085 cites W2073564719 @default.
• W2795006085 cites W2077945442 @default.
• W2795006085 cites W2078237397 @default.
• W2795006085 cites W2080020076 @default.
• W2795006085 cites W2084566861 @default.
• W2795006085 cites W2085350707 @default.
• W2795006085 cites W2089138607 @default.
• W2795006085 cites W2090612886 @default.
• W2795006085 cites W2093131958 @default.
• W2795006085 cites W2094731216 @default.
• W2795006085 cites W2115469199 @default.
• W2795006085 cites W2120055287 @default.
• W2795006085 cites W2128676243 @default.
• W2795006085 cites W2150288531 @default.
• W2795006085 cites W2159081128 @default.
• W2795006085 cites W2170265639 @default.
• W2795006085 cites W2266953687 @default.
• W2795006085 cites W2277482974 @default.
• W2795006085 cites W2315776822 @default.
• W2795006085 cites W2323902431 @default.
• W2795006085 cites W2325265107 @default.
• W2795006085 cites W2328967289 @default.
• W2795006085 cites W2333946702 @default.
• W2795006085 cites W2337685078 @default.
• W2795006085 cites W2338186405 @default.
• W2795006085 cites W2409203234 @default.
• W2795006085 cites W2413145276 @default.
• W2795006085 cites W2463360277 @default.
• W2795006085 cites W2465461534 @default.
• W2795006085 cites W2467444326 @default.
• W2795006085 cites W249197861 @default.
• W2795006085 cites W2529942289 @default.
• W2795006085 cites W2534737939 @default.
• W2795006085 cites W2552494213 @default.
• W2795006085 cites W2557021920 @default.
• W2795006085 cites W2561523394 @default.
• W2795006085 cites W2580326302 @default.
• W2795006085 cites W2632610383 @default.
• W2795006085 cites W2738549633 @default.
• W2795006085 cites W2745847245 @default.
• W2795006085 cites W2751453030 @default.
• W2795006085 cites W624074743 @default.
• W2795006085 cites W879983400 @default.
• W2795006085 doi "https://doi.org/10.1016/j.apcatb.2018.03.088" @default.

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