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- W2795056164 abstract "Raman spectra of boron-concentrated, diluted, and corresponding mother solutions of brine were recorded at 298.15 K. The main polyborate anions present and their interactions in brine during evaporation and dilution were proposed according to the Raman spectra. The polyborate anions B(OH)3, B3O3(OH)4−, B5O6(OH)4−, and B6O7(OH)62− were found to be the main forms in boron-concentrated brine with B3O3(OH)4− ion being the principal form. Diluting brines with water accelerated depolymerization of B5O6(OH)4− and B6O7(OH)62− anions into B(OH)3 and B3O3(OH)4− ions and generated OH– ions, causing the pH of the solutions to increase from 4.2 to almost 8.0. Mg-borates precipitated from all diluted solutions could be classified as either hexaborates or triborates. A mechanism of solid phase transformation was also proposed and discussed based on Raman spectra analysis and solid species and solution pH data." @default.
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- W2795056164 date "2018-06-01" @default.
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- W2795056164 title "Investigations on Mg-borate kinetics and mechanisms during evaporation, dilution and crystallization by Raman spectroscopy" @default.
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- W2795056164 doi "https://doi.org/10.1016/j.saa.2018.03.063" @default.
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