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- W2795148378 abstract "The regioselective synthesis of novel 1,5- and 1,4,5-substituted 1,2,3-triazoles linked to the β-position of 5,10,15,20-tetraphenylporphyrins and their zincated derivatives were achieved via an organocatalytic multicomponent reaction, starting from easily available β-formyl 5,10,15,20-tetraphenylporphyrin, nitroalkanes and benzyl azide, in moderate yields. The properties of these new β-linked 1,2,3-triazolyl porphyrins were investigated and atropoisomerism was observed. The rotational stability of these β-linked triazolylporphyrins, deduced by 1H NMR, was calculated and all newly synthesized compounds were further characterized by UV-VIS spectroscopy and high resolution mass spectroscopy." @default.
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- W2795148378 date "2018-09-01" @default.
- W2795148378 modified "2023-10-06" @default.
- W2795148378 title "Synthesis and characterization of novel axially chiral β-linked 1,2,3-triazolyl porphyrins" @default.
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- W2795148378 doi "https://doi.org/10.1016/j.dyepig.2018.03.056" @default.
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