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- W2795187130 abstract "Potential-dependent double-resonance sum frequency generation (DR-SFG) spectroscopy is used to probe a 5σa electronic state of adsorbed CO on Pt thin layer modified Au surfaces in acid solution by showing an amplitude enhancement of atop CO peak due to a surface electronic resonance between visible light and the electronic transition from the Fermi level of Pt to the 5σa antibonding state of CO. The energy level of 5σa state of adsorbed CO on the Pt layer-modified Au electrodes is found to be different from that on bulk Pt electrodes and depend on the thickness of the Pt layer. The observed SFG results are tentatively explained by the shift in d-band energy of the electrode substrates, which could also be responsible for their different electrochemical characteristics toward CO oxidation." @default.
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- W2795187130 date "2018-03-28" @default.
- W2795187130 modified "2023-09-29" @default.
- W2795187130 title "Electronic Structure of CO Adsorbed on Electrodeposited Pt Thin Layers on Polycrystalline Au Electrodes Probed by Potential-Dependent IR/Visible Double-Resonance Sum Frequency Generation Spectroscopy" @default.
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- W2795187130 doi "https://doi.org/10.1021/acs.jpcc.7b10703" @default.
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