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• W2795384195 abstract "Abstract Herein we report a general method of the asymmetric synthesis of 1,4‐substituted 1,2,3‐triazole containing amino acids via copper(I) iodide catalyzed “click reaction” between azides and chiral Ni(II) complexes of Schiff bases of ( S )‐ or ( R )‐BPB with alkyne side chain derivatised amino acids. The final Ni(II) complexes were decomposed with aqueous HCl and the 1,4‐substituted 1,2,3‐triazole containing amino acids isolated with excellent enantioselectivities (>99% ee ). The chiral auxiliary ligand (BPB= N ‐benzyl proline benzophenone) can be recycled and reused for the synthesis of starting Ni(II) complexes." @default.
• W2795384195 created "2018-04-13" @default.
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• W2795384195 date "2018-03-22" @default.
• W2795384195 modified "2023-10-16" @default.
• W2795384195 title "The Elaboration of a General Approach to the Asymmetric Synthesis of 1,4-Substituted 1,2,3-Triazole Containing Amino Acids <i>via</i> Ni(II) Complexes" @default.
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• W2795384195 doi "https://doi.org/10.1002/slct.201800228" @default.
• W2795384195 hasPublicationYear "2018" @default.
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