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- W2795476253 abstract "Allylic sulfones were synthesized with excellent selectivity and good yield via Pd-catalyzed cross-coupling of vinyl iodide with N-tosylhydrazone. This process involves palladium carbene migratory insertion/trapping with sulfinic acid salts. For the previous Pd-catalyzed N-tosylhydrazone cross-coupling, sulfinic acid salt is generated as a byproduct. In this transformation, the diazo compound and the sulfinic acid salt, which are all generated from N-tosylhydrazone, were used as cross-coupling partner." @default.
- W2795476253 created "2018-04-13" @default.
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- W2795476253 date "2018-04-05" @default.
- W2795476253 modified "2023-10-06" @default.
- W2795476253 title "Palladium-Catalyzed Carbene Migratory Insertion and Trapping with Sulfinic Acid Salts toward Allylic Sulfones" @default.
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- W2795476253 doi "https://doi.org/10.1021/acs.joc.8b00615" @default.
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