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• W2795683888 abstract "Hydrazinium azide (HA) has been investigated at high pressures to 68 GPa using confocal micro-Raman spectroscopy and synchrotron powder x-ray diffraction. The results show that HA undergoes structural phase transitions from solid HA-I to HA-II at 13 GPa, associated with the strengthening of hydrogen bonding, and then to N8 at 40 GPa. The transformation of HA to recently predicted N8 (N≡N+—N−—N=N—−N—+N≡N) is evident by the emergence of new peaks at 2384 cm−1, 1665 cm−1, and 1165 cm−1, arising from the terminal N≡N stretching, the central N=N stretching, and the N—N stretching, respectively. However, upon decompression, N8 decomposes to ε-N2 below 25 GPa, but the remnant can be seen as low as 3 GPa." @default.
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• W2795683888 date "2018-04-06" @default.
• W2795683888 modified "2023-10-16" @default.
• W2795683888 title "Transformation of hydrazinium azide to molecular N₈ at 40 GPa" @default.
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• W2795683888 doi "https://doi.org/10.1063/1.5021976" @default.
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