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- W2795687764 endingPage "422" @default.
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- W2795687764 abstract "Light and acid steer a radical addition So-called Minisci reactions have been used for decades in pharmaceutical and agrochemical synthesis to make carbon-carbon bonds. The reactions link carbon radicals to the carbon centers adjacent to nitrogen in pyridine rings. Proctor et al. devised a method to steer these reactions to just one of two possible mirror-image products. To make the radicals, they prepared derivatives of widely available amino acids and then activated them with an iridium photocatalyst. At the same time, a chiral phosphoric acid catalyst was used to activate the pyridine and bias the reaction geometry. Science , this issue p. 419" @default.
- W2795687764 created "2018-04-13" @default.
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- W2795687764 date "2018-04-27" @default.
- W2795687764 modified "2023-10-16" @default.
- W2795687764 title "Catalytic enantioselective Minisci-type addition to heteroarenes" @default.
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- W2795687764 doi "https://doi.org/10.1126/science.aar6376" @default.
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