FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2796004428> ?p ?o ?g. }

• W2796004428 endingPage "13684" @default.
• W2796004428 startingPage "13675" @default.
• W2796004428 abstract "The development of earth-abundant, highly active, and corrosion-resistant electrocatalysts to promote the oxygen reduction reaction (ORR) and oxygen and hydrogen evolution reactions (OER/HER) for rechargeable metal–air batteries and water-splitting devices is urgently needed. In this work, NixSe (0.5 ≤ x ≤ 1) nanocrystals with different crystal structures and compositions have been controllably synthesized and investigated as potential electrocatalysts for multifunctional ORR, OER, and HER in alkaline conditions. A novel hot-injection process at ambient pressure was developed to control the phase and composition of a series of NixSe by simply adjusting the added molar ratio of the nickel resource to triethylenetetramine. Electrochemical analysis reveals that Ni0.5Se nanocrystalline exhibits superior OER activity compared to its counterparts and is comparable to RuO2 in terms of the low overpotential required to reach a current density of 10 mA cm–2 (330 mV), which may benefit from the pyrite-type crystal structure and Se enrichment in Ni0.5Se. For the ORR and HER, Ni0.75Se nanoparticles achieve the best performance including lower overpotentials and larger apparent current densities. Further investigations demonstrate that Ni0.75Se could not only provide an enhanced electrochemical active area but also facilitate electron transfer during the electrocatalytic process, thus contributing to the remarkable catalytic activity. As a practical application, the Ni0.75Se electrode enables rechargeable Zn–air battery with a considerable performance including a long cycling lifetime (200 cycles), high specific capacity (609 mA h g–1 based on the consumed Zn), and low overpotential (0.75 V) at 10 mA cm–2. Meanwhile, the water-splitting cell setup with an anode of Ni0.5Se for the HER and a cathode of Ni0.75Se for the OER exhibits a considerable performance with low decay in activity of 12.9% under continuous polarization for 10 h. These results suggest the promising potential of nickel selenide nanocrystals as earth-abundant and high-performance electrocatalysts for metal–air batteries and alkaline water splitting." @default.
• W2796004428 created "2018-04-13" @default.
• W2796004428 creator A5008178438 @default.
• W2796004428 creator A5022438535 @default.
• W2796004428 creator A5025874763 @default.
• W2796004428 creator A5039974377 @default.
• W2796004428 creator A5044301848 @default.
• W2796004428 creator A5057326412 @default.
• W2796004428 creator A5066703660 @default.
• W2796004428 creator A5069789783 @default.
• W2796004428 creator A5073977425 @default.
• W2796004428 date "2018-04-04" @default.
• W2796004428 modified "2023-10-16" @default.
• W2796004428 title "Controllable Synthesis of Ni_<i>x</i>Se (0.5 ≤ <i>x</i> ≤ 1) Nanocrystals for Efficient Rechargeable Zinc–Air Batteries and Water Splitting" @default.
• W2796004428 cites W1734768115 @default.
• W2796004428 cites W1946340942 @default.
• W2796004428 cites W1971113415 @default.
• W2796004428 cites W1984781904 @default.
• W2796004428 cites W1992124490 @default.
• W2796004428 cites W2015124676 @default.
• W2796004428 cites W2019360373 @default.
• W2796004428 cites W2039317142 @default.
• W2796004428 cites W2041209948 @default.
• W2796004428 cites W2050968817 @default.
• W2796004428 cites W2058020696 @default.
• W2796004428 cites W2060750246 @default.
• W2796004428 cites W2089998452 @default.
• W2796004428 cites W2096975427 @default.
• W2796004428 cites W2106994275 @default.
• W2796004428 cites W2117913892 @default.
• W2796004428 cites W2133355241 @default.
• W2796004428 cites W2183896395 @default.
• W2796004428 cites W2204713405 @default.
• W2796004428 cites W2264947591 @default.
• W2796004428 cites W2281254134 @default.
• W2796004428 cites W2287936852 @default.
• W2796004428 cites W2334952434 @default.
• W2796004428 cites W2402325423 @default.
• W2796004428 cites W2428990000 @default.
• W2796004428 cites W2435301856 @default.
• W2796004428 cites W2468875794 @default.
• W2796004428 cites W2483492124 @default.
• W2796004428 cites W2519490890 @default.
• W2796004428 cites W2531523996 @default.
• W2796004428 cites W2532893770 @default.
• W2796004428 cites W2558157656 @default.
• W2796004428 cites W2559337944 @default.
• W2796004428 cites W2560652318 @default.
• W2796004428 cites W2561229584 @default.
• W2796004428 cites W2591070449 @default.
• W2796004428 cites W2602209176 @default.
• W2796004428 cites W2611118998 @default.
• W2796004428 cites W2614522063 @default.
• W2796004428 cites W2616040970 @default.
• W2796004428 cites W2616706645 @default.
• W2796004428 cites W2618285996 @default.
• W2796004428 cites W2737682966 @default.
• W2796004428 cites W2748463679 @default.
• W2796004428 cites W2750851534 @default.
• W2796004428 cites W2752366461 @default.
• W2796004428 cites W2752755596 @default.
• W2796004428 cites W2753913538 @default.
• W2796004428 cites W2756451010 @default.
• W2796004428 cites W2760601679 @default.
• W2796004428 cites W2774108120 @default.
• W2796004428 cites W2780785870 @default.
• W2796004428 cites W2786658823 @default.
• W2796004428 doi "https://doi.org/10.1021/acsami.8b01651" @default.
• W2796004428 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29616794" @default.
• W2796004428 hasPublicationYear "2018" @default.
• W2796004428 type Work @default.
• W2796004428 sameAs 2796004428 @default.
• W2796004428 citedByCount "104" @default.
• W2796004428 countsByYear W27960044282018 @default.
• W2796004428 countsByYear W27960044282019 @default.
• W2796004428 countsByYear W27960044282020 @default.
• W2796004428 countsByYear W27960044282021 @default.
• W2796004428 countsByYear W27960044282022 @default.
• W2796004428 countsByYear W27960044282023 @default.
• W2796004428 crossrefType "journal-article" @default.
• W2796004428 hasAuthorship W2796004428A5008178438 @default.
• W2796004428 hasAuthorship W2796004428A5022438535 @default.
• W2796004428 hasAuthorship W2796004428A5025874763 @default.
• W2796004428 hasAuthorship W2796004428A5039974377 @default.
• W2796004428 hasAuthorship W2796004428A5044301848 @default.
• W2796004428 hasAuthorship W2796004428A5057326412 @default.
• W2796004428 hasAuthorship W2796004428A5066703660 @default.
• W2796004428 hasAuthorship W2796004428A5069789783 @default.
• W2796004428 hasAuthorship W2796004428A5073977425 @default.
• W2796004428 hasConcept C121332964 @default.
• W2796004428 hasConcept C127413603 @default.
• W2796004428 hasConcept C135473242 @default.
• W2796004428 hasConcept C140676511 @default.
• W2796004428 hasConcept C147789679 @default.
• W2796004428 hasConcept C161790260 @default.
• W2796004428 hasConcept C163258240 @default.
• W2796004428 hasConcept C171250308 @default.
• W2796004428 hasConcept C17525397 @default.

• next