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• W2796191305 startingPage "384" @default.
• W2796191305 abstract "In this study, N-doped mesoporous carbon ropes (N-MCRs), derived from polybenzoxazine, a new high-performance thermosetting resin, used as an electrode active material for supercapacitor application. Nitrogen-containing tetraethylenepentamine and eugenol were used to synthesize polybenzoxazine. The structure of the monomer was supported by Fourier transform infrared (FT-IR) and 1H NMR spectroscopy. The morphology and surface properties of the synthesized N-MCRs were investigated by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), N2 adsorption-desorption study and X-ray photoelectron spectroscopy (XPS). It was found that the reactant ratio of nitrogen-rich polybenzoxazine plays an important role in the improvement of electrochemical behavior. The BET surface area of N-MCRs was found to be 300 m2 g−1. Electrochemical performance proposes a high nitrogen content of 12.38 mol % with optimum nitrogen-containing benzoxazine derived carbon backgrounds. It showed a specific capacitance of the 60 F g−1 in 2 M KOH aqueous electrolyte at a current density of 1 A g−1. A remarkable improvement in the electrochemical behavior was obtained by modifying the surface chemistry as well as the electrical conductivity of the carbon. The presence of porous carbon with intrinsic nitrogen-containing groups makes them more useful as high-performance supercapacitor. Overall, this simple approach exhibits great potential for carbon-based high-performance supercapacitor application." @default.
• W2796191305 created "2018-04-13" @default.
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• W2796191305 date "2018-06-01" @default.
• W2796191305 modified "2023-09-26" @default.
• W2796191305 title "Polybenzoxazine originated N-doped mesoporous carbon ropes as an electrode material for high-performance supercapacitors" @default.
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• W2796191305 doi "https://doi.org/10.1016/j.jallcom.2018.04.034" @default.
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