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- W2796277066 endingPage "1761" @default.
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- W2796277066 abstract "Cost-efficient thin-film devices that emit in the near-infrared (NIR) range promise a wide range of important applications. Here, the synthesis and NIR application of a series of copolymers comprising poly[indacenodithieno[3,2-b]thiophene-2,8-diyl] (PIDTT) as the host and different donor–acceptor–donor (DAD) segments as the guest are reported. We find that a key design criterion for efficient solid-state host-to-guest energy transfer is that the DAD conformation is compatible with the conformation of the host. Such host–guest copolymers are evaluated as the emitter in light-emitting electrochemical cells (LECs) and organic light-emitting diodes, and the best performance is invariably attained from the LEC devices because of the observed balanced electrochemical doping that alleviates issues with a noncentered emission zone. An LEC device comprising a host–guest copolymer with 4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b′]dithiophene as the donor and benzo[c][1,2,5]thiadiazole as the acceptor delivers an im..." @default.
- W2796277066 created "2018-04-13" @default.
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- W2796277066 date "2018-04-04" @default.
- W2796277066 modified "2023-10-16" @default.
- W2796277066 title "Incorporation of Designed Donor–Acceptor–Donor Segments in a Host Polymer for Strong Near-Infrared Emission from a Large-Area Light-Emitting Electrochemical Cell" @default.
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- W2796277066 doi "https://doi.org/10.1021/acsaem.8b00283" @default.
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