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- W2796571865 abstract "A thiol-promoted site-specific addition of 1,3-dioxolane to imines through a radical chain process is described. This process represents a metal-free and redox-neutral way to convert inexpensive materials to a broad range of protected α-amino aldehydes in good to excellent yields using only a catalytic amount of radical precursor. Control experiments revealed that both the thiol and a small amount of oxygen from air are indispensable to the success of this reaction." @default.
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- W2796571865 date "2018-04-12" @default.
- W2796571865 modified "2023-10-18" @default.
- W2796571865 title "Site-Specific Functionalization of 1,3-Dioxolane with Imines: A Radical Chain Approach to Masked α-Amino Aldehydes" @default.
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- W2796571865 doi "https://doi.org/10.1021/acs.joc.8b00715" @default.
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