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• W2796599701 abstract "New insights into the process of high‐temperature trifluoromethylation of polycyclic aromatic hydrocarbons (PAHs) were gained in a detailed study of the reactions between corannulene (C 20 H 10 ) and CF 3 I gas. Ten new poly(trifluoromethyl)corannulenes were made in these reactions and were fully characterized. A detailed computational study explains the observed trends in the product distribution and why some products cannot be prepared even with an excess of the reagent gas. The approach utilized here may have good predictive value for designing new effective and selective synthetic methodologies for various thermally stable electron‐deficient PAHs." @default.
• W2796599701 created "2018-04-24" @default.
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• W2796599701 date "2018-07-19" @default.
• W2796599701 modified "2023-09-30" @default.
• W2796599701 title "Understanding Polyarene Trifluoromethylation with Hot CF ₃ Radicals Using Corannulene" @default.
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• W2796599701 doi "https://doi.org/10.1002/ejoc.201800508" @default.
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