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• W2796625157 startingPage "6702" @default.
• W2796625157 abstract "Two types of (acetylide)(triethylphosphine)gold(i) complexes ArCOC[triple bond, length as m-dash]CAuPEt3 (1a and 1b) and ArC[triple bond, length as m-dash]CAuPEt3 (2a and 2b) bearing Ar = pyren-1-yl or ferrocenyl group were synthesized and the effect of a carbonyl moiety on the structure, propensity to ligand scrambling in solution and luminescence properties were investigated. We found that the complexes bearing acetylenic ketone-derived ligands underwent ligand scrambling in solution to afford mixtures of ArCOC[triple bond, length as m-dash]CAuPEt3 and [(ArCOC[triple bond, length as m-dash]C)2Au]-[Au(PEt3)2]+. The latter complexes were isolated and their structures were confirmed by single crystal X-ray diffraction studies. The aurophilic interaction of AuAu in these complexes resulted in the formation of wire-like structures." @default.
• W2796625157 created "2018-04-24" @default.
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• W2796625157 date "2018-01-01" @default.
• W2796625157 modified "2023-10-18" @default.
• W2796625157 title "(Ar–CO–CC)(PEt₃)Au and (Ar–CC)(PEt₃)Au complexes bearing pyrenyl and ferrocenyl groups: synthesis, structure, and luminescence properties" @default.
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• W2796625157 doi "https://doi.org/10.1039/c8dt01061g" @default.
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• W2796625157 hasPublicationYear "2018" @default.
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