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- W2796699782 abstract "The electrochemical investigation of L-histidine in aqueous phosphate buffers at pH 7.4 and 11 has shown that L-histidine oxidation at glassy carbon occurs as a chemically irreversible process, and the current response is nonlinear with concentration. The oxidation potentials are more positive than those observed for L-cysteine under corresponding conditions. For this reason, cyclic voltammetric behavior at gold is dominated by the oxide formation process on the gold surface. The complexation of Zn2+ and Cu2+ by L-histidine in pH 7.4 MOPS buffer has been studied by square wave voltammetric (SWV) methods by considering the peak potential shift between the metal stripping peak (E0 estimate) and the peak potential for the ML2 complex reduction. Attempts to observe characteristic mass peaks from MALDI experiments for the zinc and copper complexes with L-histidine and L-cysteine at ML2 compositions yielded no definitive results." @default.
- W2796699782 created "2018-04-24" @default.
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- W2796699782 date "2018-06-19" @default.
- W2796699782 modified "2023-09-27" @default.
- W2796699782 title "Electrochemical Studies of L-Histidine" @default.
- W2796699782 doi "https://doi.org/10.1149/08513.1123ecst" @default.
- W2796699782 hasPublicationYear "2018" @default.
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