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- W2796989233 abstract "All-inorganic self-arranged molecular transition metal oxide hyperstructures based on polyoxometalate molecules (POMs) are fabricated and tested as electronically tunable components in emerging electronic devices. POM hyperstructures reveal great potential as charging nodes of tunable charging level for molecular memories and as enhancers of interfacial electron/hole injection for photovoltaic stacks. STM, UPS, UV-vis spectroscopy and AFM measurements show that this functionality stems from the films' ability to structurally tune their HOMO-LUMO levels and electron localization length at room temperature. By adapting POM nanocluster size in solution, self-doping and current modulation of four orders of magnitude is monitored on a single nanocluster on SiO2 at voltages as low as 3 Volt. Structurally driven insulator-to-semi-metal transitions and size-dependent current regulation through single electron tunneling are demonstrated and examined with respect to the stereochemical and electronic structure of the molecular entities. This extends the value of self-assembly as a tool for correlation length and electronic properties tuning and demonstrate POM hyperstructures' plausibility for on-chip molecular electronics operative at room temperature." @default.
- W2796989233 created "2018-04-24" @default.
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- W2796989233 date "2018-05-09" @default.
- W2796989233 modified "2023-09-30" @default.
- W2796989233 title "Size-dependent single electron transfer and semi-metal-to-insulator transitions in molecular metal oxide electronics" @default.
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- W2796989233 cites W1964344793 @default.
- W2796989233 cites W1966325235 @default.
- W2796989233 cites W1967760164 @default.
- W2796989233 cites W1976849993 @default.
- W2796989233 cites W1977166085 @default.
- W2796989233 cites W1978403538 @default.
- W2796989233 cites W1984836820 @default.
- W2796989233 cites W1991878882 @default.
- W2796989233 cites W1993189322 @default.
- W2796989233 cites W1996913248 @default.
- W2796989233 cites W2000024623 @default.
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- W2796989233 cites W2002089816 @default.
- W2796989233 cites W2005844033 @default.
- W2796989233 cites W2012222057 @default.
- W2796989233 cites W2012391906 @default.
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- W2796989233 cites W2015673981 @default.
- W2796989233 cites W2016613982 @default.
- W2796989233 cites W2018079381 @default.
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- W2796989233 doi "https://doi.org/10.1088/1361-6528/aabdc3" @default.
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- W2796989233 hasPublicationYear "2018" @default.
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