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- W2797029759 abstract "Abstract This article reviews enzymatic preparation of functional polysaccharide hydrogels by means of phosphorylase-catalyzed enzymatic polymerization. A first topic of this review deals with the synthesis of amylose-grafted polymeric materials and their formation of hydrogels, composed of abundant natural polymeric main-chains, such as chitosan, cellulose, xantham gum, carboxymethyl cellulose, and poly(γ-glutamic acid). Such synthesis was achieved by combining the phosphorylase-catalyzed enzymatic polymerization forming amylose with the appropriate chemical reaction (chemoenzymatic method). An amylose-grafted chitin nanofiber hyrogel was also prepared by the chemoenzymatic approach. As a second topic, the preparation of glycogen hydrogels by the phosphorylase-catalyzed enzymatic reactions was described. When the phosphorylase-catalyzed enzymatic polymerization from glycogen as a polymeric primer was carried out, followed by standing the reaction mixture at room temperature, a hydrogel was obtained. pH-Responsive amphoteric glycogen hydrogels were also fabricated by means of the successive phosphorylase-catalyzed enzymatic reactions." @default.
- W2797029759 created "2018-04-24" @default.
- W2797029759 creator A5040487927 @default.
- W2797029759 date "2018-03-02" @default.
- W2797029759 modified "2023-09-24" @default.
- W2797029759 title "Enzymatic preparation of functional polysaccharide hydrogels by phosphorylase catalysis" @default.
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- W2797029759 doi "https://doi.org/10.1515/pac-2017-0802" @default.
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