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- W2797264987 abstract "Abstract A facile and direct method for the construction of enantioenriched α‐arylated quaternary β‐ketoamides was developed. By employing a chiral bifunctional thiourea‐tertiary amine as catalyst, enantioselective α‐arylation of cyclic β‐ketoamides with a quinone monoimine proceeded smoothly to afford various α‐arylated quaternary β‐ketoamides in good yields (up to 97%) with moderate to good enantioselectivities (up to 85% ee). Generally, benzo six‐membered cyclic β‐ketoamides exhibited better enantioselection than benzo five‐membered cyclic β‐ketoamides." @default.
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- W2797264987 date "2018-04-14" @default.
- W2797264987 modified "2023-10-14" @default.
- W2797264987 title "Enantioselective α-Arylation of Cyclic β-Ketoamides with a Quinone Monoimine" @default.
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- W2797264987 doi "https://doi.org/10.1002/slct.201800085" @default.
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