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- W2797522685 abstract "Abstract Cobalt phosphides (CoP x ) are potential candidates for use as high‐efficiency hydrogen evolution reaction electrocatalysts that can replace noble metals, such as Pt. Typically, CoP x can be synthesized by phosphidation with Co‐based precursors such as oxides or hydroxides. In this study, we propose a new strategy for synthesizing CoP x through the thermal reduction in cobalt phosphate (Co 3 ( PO 4 ) 2 ). A reduced graphene oxide‐wrapped CoP/Co 2 P hybrid microflower was successfully synthesized by a facile coprecipitation method in a Co 3 ( PO 4 ) 2 matrix, followed by a thermal reduction process. Co 3 ( PO 4 ) 2 can be transformed to CoP/Co 2 P by treatment at 700°C for 1 hour, maintaining the original particle morphology with the assistance of reduced graphene oxide ( rGO ). In a 0.5 mol/L H 2 SO 4 solution, the rGO ‐CoP/Co 2 P microflower catalyzes the hydrogen evolution reaction with an overpotential of 156 mV at a current density of 10 mA cm −2 , a Tafel slope of 53.8 mV dec −1 , and good stability as observed through long‐term CV and chronoamperometry tests." @default.
- W2797522685 created "2018-04-24" @default.
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- W2797522685 date "2018-04-17" @default.
- W2797522685 modified "2023-09-24" @default.
- W2797522685 title "Thermally reduced <scp>rGO</scp> ‐wrapped CoP/Co <sub>2</sub> P hybrid microflower as an electrocatalyst for hydrogen evolution reaction" @default.
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- W2797522685 doi "https://doi.org/10.1111/jace.15581" @default.
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