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- W2797628088 abstract "NiMn layered hydroxide compounds have been found to be efficient catalysts for the oxidative dehydrogenation of N-heterocycles by molecular oxygen under mild conditions. Various tetrahydroquinoline derivatives and some other N-heterocycles have been found to be tolerated by the catalytic system. A synergistic effect between Ni and Mn has been observed in the reaction. A kinetic study concluded that the dehydrogenation of 1,2,3,4-tetrahydroquinoline is a first-order reaction, and an apparent activation energy of 113 kJ/mol has been obtained. A probable reaction mechanism comprising an imine intermediate has been proposed according to the obtained results and XPS analysis. The key catalytic site for the dehydrogenation is thought to be Mn3+, which could be stabilized by Ni2+ in the hydrotalcite structure." @default.
- W2797628088 created "2018-04-24" @default.
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- W2797628088 date "2018-05-01" @default.
- W2797628088 modified "2023-10-12" @default.
- W2797628088 title "Additive-free aerobic oxidative dehydrogenation of N-heterocycles under catalysis by NiMn layered hydroxide compounds" @default.
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- W2797628088 doi "https://doi.org/10.1016/j.jcat.2018.01.030" @default.
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