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- W2797745743 endingPage "582" @default.
- W2797745743 startingPage "565" @default.
- W2797745743 abstract "Abstract The present work aimed to prepare some compounds for use in pigmented solar cells based on charge transfer (CT) complexation. For this purpose, first, several derivatives of 1,8–naphthalimide and benzanthrone fluorescent dyes were synthesized. Secondly, the synthesized fluorescent dyes were complexed with picric acid (PA) acceptor via CT interaction in methanol solvent at room temperature. Then, the synthesized CT complexes were stoichiometrically, spectroscopically and thermally characterized. The results obtained from CHN elemental analyses and spectrophotometric titrations indicated the formation of CT complexes with a molar ratio of 1:1 between the PA and each dye. The spectroscopic and physical parameters (KCT, emax, ECT, f, μ, RN, IP, and ΔG°), the band gap energy (Eg), and the kinetic–thermodynamic parameters (E⁎, A, ΔS⁎, ΔH⁎ and ΔG⁎) were calculated for each CT product in methanol solvent at room temperature. IR results indicated that the complexation between each dye and PA acceptor occurs through π → π* and proton transfer interactions." @default.
- W2797745743 created "2018-04-24" @default.
- W2797745743 creator A5008527810 @default.
- W2797745743 creator A5027838773 @default.
- W2797745743 creator A5029058310 @default.
- W2797745743 creator A5054889050 @default.
- W2797745743 creator A5056934831 @default.
- W2797745743 creator A5073419831 @default.
- W2797745743 creator A5079622912 @default.
- W2797745743 date "2018-07-01" @default.
- W2797745743 modified "2023-09-27" @default.
- W2797745743 title "Preparation of some compounds and study their thermal stability for use in dye sensitized solar cells" @default.
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