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- W2797849495 endingPage "4823" @default.
- W2797849495 startingPage "4812" @default.
- W2797849495 abstract "The mechanism of boron-to-nickel transmetalation, the key step of the nickel-catalyzed Suzuki-Miyaura (S-M) coupling, was examined both experimentally and theoretically. Dinuclear μ-hydroxo-bridged complexes formed by reaction of trans-[ArNi(PR3)2X] with hydroxide are not directly involved in transmetalation, but they rather act as a resting state for the catalyst. The base/boronic acid ratio is the crucial parameter, as it modulates the extent of formation of these dinuclear species and thus tunes the catalytic activity. These findings explain some limitations encountered in practical applications of nickel-catalyzed S-M couplings and suggest how to tailor the experimental conditions in order to overcome these difficulties." @default.
- W2797849495 created "2018-04-24" @default.
- W2797849495 creator A5000182751 @default.
- W2797849495 creator A5063417271 @default.
- W2797849495 creator A5066183192 @default.
- W2797849495 creator A5071504291 @default.
- W2797849495 date "2018-04-13" @default.
- W2797849495 modified "2023-10-05" @default.
- W2797849495 title "Taming Nickel-Catalyzed Suzuki-Miyaura Coupling: A Mechanistic Focus on Boron-to-Nickel Transmetalation" @default.
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