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- W2798137214 abstract "Regiocontrolled synthesis of precursors for strained cyclohexynes and 1,2‐cyclohexadienes is described based on one‐pot rearrangement of silyl enol ether followed by formation of enol triflate. Treatment of silyl enol ether with a combination of LDA and t BuOK led to the migration of the silyl group to generate α‐silyl enolate, which was treated with Comins' reagent to provide the corresponding enol triflate. The transient α‐silylated lithium enolate was smoothly isomerized in the presence of stoichiometric amount of water within one hour at room temperature, providing precursors for cyclohexynes exclusively in one pot. Effects of silyl groups, isomerization of the lithium enolate, and regiocontrolled generation of these precursors for these strained molecules were also investigated." @default.
- W2798137214 created "2018-04-24" @default.
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- W2798137214 date "2018-07-03" @default.
- W2798137214 modified "2023-10-15" @default.
- W2798137214 title "One-Pot Synthesis of Silylated Enol Triflates from Silyl Enol Ethers for Cyclohexynes and 1,2-Cyclohexadienes" @default.
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- W2798137214 doi "https://doi.org/10.1002/ejoc.201800353" @default.
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