FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2799431759> ?p ?o ?g. }

• W2799431759 abstract "Abstract The bioactive alkaloid natural product perophoramidine and the related family of compounds known as the communesins have inspired the synthesis community for more than a decade. Many of the elegant approaches have required the synthesis of complex intermediates that have not always reacted in the expected manner. In this study we describe a series of cyclic ether-containing precursors that were prepared during our synthetic studies towards these natural products. Attempts to open the cyclic ether ring and trap the resulting stabilised carbocation with a carbon nucleophile ultimately led to the preparation of a diallyl-substituted all carbon quaternary centre. Subsequent attempts to differentiate between the two allyl groups resulted in a relatively clean transformation to an unexpected compound. Extensive structural characterisation, including small molecule X-ray crystallography, showed that a dearomatisation reaction had occurred." @default.
• W2799431759 created "2018-05-17" @default.
• W2799431759 creator A5001147371 @default.
• W2799431759 creator A5007863617 @default.
• W2799431759 creator A5017202324 @default.
• W2799431759 creator A5020851210 @default.
• W2799431759 creator A5049970193 @default.
• W2799431759 creator A5051130517 @default.
• W2799431759 creator A5085237437 @default.
• W2799431759 date "2018-06-01" @default.
• W2799431759 modified "2023-09-24" @default.
• W2799431759 title "Polycyclic ethers and an unexpected dearomatisation reaction during studies towards the bioactive alkaloid, perophoramidine" @default.
• W2799431759 cites W1922010669 @default.
• W2799431759 cites W1965560031 @default.
• W2799431759 cites W1984790756 @default.
• W2799431759 cites W1987567713 @default.
• W2799431759 cites W1997829941 @default.
• W2799431759 cites W2003711514 @default.
• W2799431759 cites W2006178641 @default.
• W2799431759 cites W2019523924 @default.
• W2799431759 cites W2036560354 @default.
• W2799431759 cites W2058623521 @default.
• W2799431759 cites W2061402182 @default.
• W2799431759 cites W2062994795 @default.
• W2799431759 cites W2064686321 @default.
• W2799431759 cites W2065817032 @default.
• W2799431759 cites W2066977331 @default.
• W2799431759 cites W2068146770 @default.
• W2799431759 cites W2071553185 @default.
• W2799431759 cites W2075172366 @default.
• W2799431759 cites W2092658289 @default.
• W2799431759 cites W2095617202 @default.
• W2799431759 cites W2106792101 @default.
• W2799431759 cites W2118807855 @default.
• W2799431759 cites W2144903206 @default.
• W2799431759 cites W2151439412 @default.
• W2799431759 cites W2153017230 @default.
• W2799431759 cites W2165560709 @default.
• W2799431759 cites W2213241409 @default.
• W2799431759 cites W2312918110 @default.
• W2799431759 cites W2413503343 @default.
• W2799431759 cites W2493187597 @default.
• W2799431759 cites W2585831817 @default.
• W2799431759 cites W2590179639 @default.
• W2799431759 cites W2614829905 @default.
• W2799431759 cites W2949465528 @default.
• W2799431759 cites W2950615361 @default.
• W2799431759 doi "https://doi.org/10.1016/j.tet.2018.04.086" @default.
• W2799431759 hasPublicationYear "2018" @default.
• W2799431759 type Work @default.
• W2799431759 sameAs 2799431759 @default.
• W2799431759 citedByCount "4" @default.
• W2799431759 countsByYear W27994317592019 @default.
• W2799431759 countsByYear W27994317592020 @default.
• W2799431759 countsByYear W27994317592021 @default.
• W2799431759 crossrefType "journal-article" @default.
• W2799431759 hasAuthorship W2799431759A5001147371 @default.
• W2799431759 hasAuthorship W2799431759A5007863617 @default.
• W2799431759 hasAuthorship W2799431759A5017202324 @default.
• W2799431759 hasAuthorship W2799431759A5020851210 @default.
• W2799431759 hasAuthorship W2799431759A5049970193 @default.
• W2799431759 hasAuthorship W2799431759A5051130517 @default.
• W2799431759 hasAuthorship W2799431759A5085237437 @default.
• W2799431759 hasBestOaLocation W27994317592 @default.
• W2799431759 hasConcept C109057382 @default.
• W2799431759 hasConcept C161790260 @default.
• W2799431759 hasConcept C161904146 @default.
• W2799431759 hasConcept C178790620 @default.
• W2799431759 hasConcept C178907741 @default.
• W2799431759 hasConcept C185592680 @default.
• W2799431759 hasConcept C21951064 @default.
• W2799431759 hasConcept C2777667214 @default.
• W2799431759 hasConcept C2779396153 @default.
• W2799431759 hasConcept C2780378348 @default.
• W2799431759 hasConcept C2780407432 @default.
• W2799431759 hasConcept C32909587 @default.
• W2799431759 hasConcept C35753019 @default.
• W2799431759 hasConcept C71240020 @default.
• W2799431759 hasConceptScore W2799431759C109057382 @default.
• W2799431759 hasConceptScore W2799431759C161790260 @default.
• W2799431759 hasConceptScore W2799431759C161904146 @default.
• W2799431759 hasConceptScore W2799431759C178790620 @default.
• W2799431759 hasConceptScore W2799431759C178907741 @default.
• W2799431759 hasConceptScore W2799431759C185592680 @default.
• W2799431759 hasConceptScore W2799431759C21951064 @default.
• W2799431759 hasConceptScore W2799431759C2777667214 @default.
• W2799431759 hasConceptScore W2799431759C2779396153 @default.
• W2799431759 hasConceptScore W2799431759C2780378348 @default.
• W2799431759 hasConceptScore W2799431759C2780407432 @default.
• W2799431759 hasConceptScore W2799431759C32909587 @default.
• W2799431759 hasConceptScore W2799431759C35753019 @default.
• W2799431759 hasConceptScore W2799431759C71240020 @default.
• W2799431759 hasFunder F4320334627 @default.
• W2799431759 hasLocation W27994317591 @default.
• W2799431759 hasLocation W27994317592 @default.
• W2799431759 hasOpenAccess W2799431759 @default.
• W2799431759 hasPrimaryLocation W27994317591 @default.
• W2799431759 hasRelatedWork W2004421645 @default.
• W2799431759 hasRelatedWork W2025061882 @default.
• W2799431759 hasRelatedWork W2065392887 @default.

• next