FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2799502015> ?p ?o ?g. }

• W2799502015 endingPage "979" @default.
• W2799502015 startingPage "969" @default.
• W2799502015 abstract "A novel means of achieving chiral separations in supercritical fluid chromatography (SFC) using a water stationary phase is presented. By adding various chiral selectors to the phase, different chiral analytes can be readily separated using neat CO2 as a mobile phase. For example, by adding β-cyclodextrin, it is found that certain flavanone enantiomers can be separated, while using the antibiotic vancomycin as a selector provides separation of some chiral phenoxypropionic acids. Other additives such as sodium chloride and triethylamine are also explored and found to enhance certain separations when also present in the water phase. While column pressure has a moderate impact on chiral analyte retention and separation in this SFC method, column temperature has a comparatively larger influence. In particular, relatively cooler temperatures below about 5 °C are found to markedly increase resolution and selectivity. For instance, notably large resolution of 4.7 is achieved for a phenoxypropionic acid pair at 0 °C and 150 atm CO2. Since the method does not require modifier to elute such polar species, it is also readily compatible with FID detection and does not generate organic waste. Therefore, results indicate that this approach could be a potentially simple and flexible means of achieving chiral separations in SFC." @default.
• W2799502015 created "2018-05-17" @default.
• W2799502015 creator A5007289411 @default.
• W2799502015 creator A5079665101 @default.
• W2799502015 date "2018-05-04" @default.
• W2799502015 modified "2023-09-29" @default.
• W2799502015 title "Chiral Separations Using a Modified Water Stationary Phase in Supercritical Fluid Chromatography" @default.
• W2799502015 cites W1976022573 @default.
• W2799502015 cites W1981287864 @default.
• W2799502015 cites W1981593787 @default.
• W2799502015 cites W1987388801 @default.
• W2799502015 cites W1993835843 @default.
• W2799502015 cites W1995037484 @default.
• W2799502015 cites W2006795139 @default.
• W2799502015 cites W2009169891 @default.
• W2799502015 cites W2009854181 @default.
• W2799502015 cites W2011455766 @default.
• W2799502015 cites W2017486643 @default.
• W2799502015 cites W2019359987 @default.
• W2799502015 cites W2025445693 @default.
• W2799502015 cites W2026792292 @default.
• W2799502015 cites W2027913277 @default.
• W2799502015 cites W2036161816 @default.
• W2799502015 cites W2037623420 @default.
• W2799502015 cites W2038334243 @default.
• W2799502015 cites W2039104539 @default.
• W2799502015 cites W2041009563 @default.
• W2799502015 cites W2041698999 @default.
• W2799502015 cites W2049809261 @default.
• W2799502015 cites W2051071764 @default.
• W2799502015 cites W2058408187 @default.
• W2799502015 cites W2063778153 @default.
• W2799502015 cites W2063854853 @default.
• W2799502015 cites W2077309829 @default.
• W2799502015 cites W2078897978 @default.
• W2799502015 cites W2086995904 @default.
• W2799502015 cites W2091621470 @default.
• W2799502015 cites W2092007809 @default.
• W2799502015 cites W2100967401 @default.
• W2799502015 cites W2118024509 @default.
• W2799502015 cites W2126985463 @default.
• W2799502015 cites W2135099597 @default.
• W2799502015 cites W2149951656 @default.
• W2799502015 cites W2151497900 @default.
• W2799502015 cites W2153266518 @default.
• W2799502015 cites W2255529199 @default.
• W2799502015 cites W2275393935 @default.
• W2799502015 cites W2314418827 @default.
• W2799502015 cites W2396895550 @default.
• W2799502015 cites W2512535372 @default.
• W2799502015 cites W2513340324 @default.
• W2799502015 cites W2528272556 @default.
• W2799502015 cites W2572267488 @default.
• W2799502015 cites W2587646225 @default.
• W2799502015 cites W4240806796 @default.
• W2799502015 doi "https://doi.org/10.1007/s10337-018-3534-0" @default.
• W2799502015 hasPublicationYear "2018" @default.
• W2799502015 type Work @default.
• W2799502015 sameAs 2799502015 @default.
• W2799502015 citedByCount "3" @default.
• W2799502015 countsByYear W27995020152019 @default.
• W2799502015 countsByYear W27995020152020 @default.
• W2799502015 countsByYear W27995020152021 @default.
• W2799502015 crossrefType "journal-article" @default.
• W2799502015 hasAuthorship W2799502015A5007289411 @default.
• W2799502015 hasAuthorship W2799502015A5079665101 @default.
• W2799502015 hasBestOaLocation W27995020151 @default.
• W2799502015 hasConcept C10390740 @default.
• W2799502015 hasConcept C118419359 @default.
• W2799502015 hasConcept C138268822 @default.
• W2799502015 hasConcept C154945302 @default.
• W2799502015 hasConcept C16838498 @default.
• W2799502015 hasConcept C178790620 @default.
• W2799502015 hasConcept C179998833 @default.
• W2799502015 hasConcept C185592680 @default.
• W2799502015 hasConcept C203147553 @default.
• W2799502015 hasConcept C2781283055 @default.
• W2799502015 hasConcept C41008148 @default.
• W2799502015 hasConcept C43617362 @default.
• W2799502015 hasConcept C44280652 @default.
• W2799502015 hasConcept C486523 @default.
• W2799502015 hasConcept C73826308 @default.
• W2799502015 hasConceptScore W2799502015C10390740 @default.
• W2799502015 hasConceptScore W2799502015C118419359 @default.
• W2799502015 hasConceptScore W2799502015C138268822 @default.
• W2799502015 hasConceptScore W2799502015C154945302 @default.
• W2799502015 hasConceptScore W2799502015C16838498 @default.
• W2799502015 hasConceptScore W2799502015C178790620 @default.
• W2799502015 hasConceptScore W2799502015C179998833 @default.
• W2799502015 hasConceptScore W2799502015C185592680 @default.
• W2799502015 hasConceptScore W2799502015C203147553 @default.
• W2799502015 hasConceptScore W2799502015C2781283055 @default.
• W2799502015 hasConceptScore W2799502015C41008148 @default.
• W2799502015 hasConceptScore W2799502015C43617362 @default.
• W2799502015 hasConceptScore W2799502015C44280652 @default.
• W2799502015 hasConceptScore W2799502015C486523 @default.
• W2799502015 hasConceptScore W2799502015C73826308 @default.
• W2799502015 hasFunder F4320334593 @default.

• next