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• W2799595598 abstract "A practical method for the nucleophilic substitution (SN) of alcohols furnishing alkyl chlorides, bromides, and iodides under stereochemical inversion in high catalytic efficacy is introduced. The fusion of diethylcyclopropenone as a simple Lewis base organocatalyst and benzoyl chloride as a reagent allows notable turnover numbers up to 100. Moreover, the use of plain acetyl chloride as a stoichiometric promotor in an invertive SN-type transformation is demonstrated for the first time. The operationally straightforward protocol exhibits high levels of stereoselectivity and scalability and tolerates a variety of functional groups." @default.
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• W2799595598 date "2018-05-10" @default.
• W2799595598 modified "2023-09-26" @default.
• W2799595598 title "Nucleophilic Substitutions of Alcohols in High Levels of Catalytic Efficiency" @default.
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• W2799595598 doi "https://doi.org/10.1021/acs.orglett.8b01023" @default.
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