Matches in SemOpenAlex for { <https://semopenalex.org/work/W2799691188> ?p ?o ?g. }
- W2799691188 abstract "Abstract Compared to the octahedral metal–organic framework CuBTC (also called HKUST-1), an interesting hexagonal prism shaped CuBTC/carboxyl-functionalized graphene composite was synthesized through a precursor-resolvothermal method. Based on structural characterization results of the composite, the mechanism of crystal morphology-control was proposed that carboxyl-functionalized graphene plays a dual role of structure-directing nucleation sites and framework linkers in the process of CuBTC crystal growth. The precursor-resolvothermal method provides an effective way to transform the morphology of metal–organic frameworks, and the results also demonstrate the possibility of using functionalized graphene to synthesize a wide range of structural motifs in metal–organic frameworks with adjustable metrics. On the basis of maintaining thermal stability, the composite exhibited about a 6% increase in CO2 capacity (from 6.39 mmol·g−1 of CuBTC to 6.77 mmol·g−1 at 273 K and 1 atm)." @default.
- W2799691188 created "2018-05-17" @default.
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- W2799691188 date "2018-07-01" @default.
- W2799691188 modified "2023-10-17" @default.
- W2799691188 title "Morphology-control synthesis of a Cu-based metal–organic framework directed by carboxyl-functionalized graphene" @default.
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- W2799691188 doi "https://doi.org/10.1016/j.poly.2018.04.031" @default.
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